This repository contains the data to our (Gevin von Witte, Aaron Himmler, Matthias Ernst, Sebastian Kozerke) two manuscripts about first-order rate equations in DNP NMR from 2023. As both manuscripts are closely related and were measured jointly, we only provide one joint repository for the two. The repository is divided into two folders: (1) The first contains the Matlab scripts used for the simulations and basic data processing (reading of raw data, calculation of DNP signals and correction for the readout RF pulses, (2) The second contains the experimental data for the three experiments, their basic processing results and the macro-analysis of the data to create the figures and tables about the experiments shown in the manuscripts The Matlab scripts contain more comments about their specific motivations and implementations. The title files of the Bruker experimental data folders usually contain a description of the particular experiment written at the time of performing the experiment.