Materials

Journal: Materials

Publisher

MDPI

ISSN

1996-1944

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Publications 1 - 10 of 78

Formation of Die Soldering and the Influence of Alloying Elements on the Intermetallic Interface
Kohlhepp, Marius; Uggowitzer, Peter; Hummel, Marc; et al. (2021)
Materials
Die soldering of die castings is a serious problem in the aluminum casting industry. The precise mechanism, the influence of the alloy composition, and the options for prevention have not yet been fully elaborated. A well-established solution for alloys with low iron content is the addition of manganese. However, up to 0.8 wt.% is necessary, which increases the amount of brittle phases in the material and consequently reduces ductility. Immersion tests with 1.2343 tool steel and pure aluminum as well as a hypoeutectic AlSi-alloy with Mn, Mo, Co, and Cr additions were carried out to systematically investigate the formation of die soldering. Three different intermetallic layers and a scattered granular intermetallic phase formed at the interface between steel and Al-alloy after immersion into the melt for a duration of 6 min at 710 °C. The combined presence of the irregular, needle-shaped β-Al5FeSi phase and the surrounding alloy was responsible for the bond between the two components. Mn and Mo inhibited the formation of the β-phase, and instead promoted the αC-Al15(Fe,X)3Si2 phase. This led to an evenly running boundary to the AlSi-alloy and thus prevented bonding. Cr has proven to be the most efficient addition against die soldering, with 0.2 wt.% being sufficient. Contrary to the other elements investigated, Cr also reduced the thickness of the intermetallic interface.
Porosity and pore size distribution of native and delignified beech wood determined by mercury intrusion porosimetry
Vitas, Selin; Segmehl, Jana S.; Burgert, Ingo; et al. (2019)
Materials
The complex hierarchical structures of biological materials in combination with outstanding property profiles are great sources of inspiration for material scientists. Based on these characteristic features, the structure of wood has been increasingly exploited to fabricate novel hierarchical and functional materials. With delignification treatments, the density and chemistry of wood can be altered, resulting in hierarchical cellulose scaffolds with enhanced porosity for the fabrication of novel hybrid materials. In the present study, focusing on acidic delignification of beech wood and its influence on porosity, we report on a structural characterization and qualitative assessment of the cellulose scaffolds using mercury intrusion porosimetry (MIP). To account for the effect of water removal from the hygroscopic structure, different drying methods—e.g., standard oven and freeze-drying—were applied. While native beech wood is characterized by the presence of macro, meso and micro pores, delignification altered the porosity, increasing the importance of the macropores in the pore size distribution. Furthermore, we showed that the final porosity obtained in the material is strongly dependent on the applied drying process. Samples delignified under harsh conditions at high temperature (mass loss of ~35%) show a 13% higher porosity after freeze-drying compared to oven-dried samples. The obtained results contribute to a better understanding of the impact of the delignification and drying processes on the porosity of cellulose scaffolds, which is of high relevance for subsequent modification and functionalization treatments.
µXRF Elemental Mapping of Bioresorbable Magnesium-Based Implants in Bone
Turyanskaya, Anna; Rauwolf, Mirjam; Grünewald, Tilman A.; et al. (2016)
Materials
This study investigated the distribution of the elemental constituents of Mg-based implants at various stages of the degradation process in surrounding bone tissue, with a focus on magnesium (Mg), as the main component of the alloy, and yttrium (Y), due to its potential adverse health effects. The measurements were performed on the implant-bearing thin sections of rat bone in a time series of implant degradation between one and 18 months. Micro X-ray fluorescence analysis (μXRF) with a special spectrometer meeting the requirements for the measurements of low-Z elements was used. It was found that the migration and accumulation behaviour of implant degradation products is element-specific. A sharp decrease in Mg was observed in the immediate vicinity of the interface and no specific accumulation or aggregation of Mg in the adjacent bone tissue was detected. By contrast, Y was found to migrate further into the bone over time and to remain in the tissue even after the complete degradation of the implant. Although the nature of Y accumulations must still be clarified, its potential health impact should be considered.
In situ and ex situ characterization of the microstructure formation in Ni-Cr-Si alloys during rapid solidification-toward alloy design for laser additive manufacturing
Li, Xiaoshuang; Zweiacker, Kai; Grolimund, Daniel; et al. (2020)
Materials
Laser beam-based deposition methods such as laser cladding or additive manufacturing of metals promises improved properties, performance, and reliability of the materials and therefore rely heavily on understanding the relationship between chemical composition, rapid solidification processing conditions, and resulting microstructural features. In this work, the phase formation of four Ni-Cr-Si alloys was studied as a function of cooling rate and chemical composition using a liquid droplet rapid solidification technique. Post mortem x-ray diffraction, scanning electron microscopy, and in situ synchrotron microbeam X-ray diffraction shows the present and evolution of the rapidly solidified microstructures. Furthermore, the obtained results were compared to standard laser deposition tests. In situ microbeam diffraction revealed that due to rapid cooling and an increasing amount of Cr and Si, metastable high-temperature silicides remain in the final microstructure. Due to more sluggish interface kinetics of intermetallic compounds than that of disorder solid solution, an anomalous eutectic structure becomes dominant over the regular lamellar microstructure at high cooling rates. The rapid solidification experiments produced a microstructure similar to the one generated in laser coating thus confirming that this rapid solidification test allows a rapid pre-screening of alloys suitable for laser beam-based processing techniques.
Microstructures and Mechanical Properties of Hybrid, Additively Manufactured Ti6Al4V after Thermomechanical Processing
Hemes, Susanne; Meiners, Frank; Sizova, Irina; et al. (2021)
Materials
In the present study, we propose a hybrid manufacturing route to produce high-quality Ti6Al4V parts, combining additive powder laser directed energy deposition (L-DED) for manufacturing of preforms, with subsequent hot forging as a thermomechanical processing (TMP) step. After L-DED, the material was hot formed at two different temperatures (930 °C and 1070 °C) and subsequently heat-treated for stress relief annealing. Tensile tests were performed on small sub-samples, taking into account different sample orientations with respect to the L-DED build direction and resulting in very good tensile strengths and ductility properties, similar or superior to the forged material. The resulting microstructure consists of very fine grained, partially globularized alpha grains, with a mean diameter ~0.8–2.3 µm, within a beta phase matrix, constituting between 2 and 9% of the sample. After forging in the sub-beta transus temperature range, the typical L-DED microstructure was no longer discernible and the anisotropy in tensile properties, common in additive manufacturing (AM), was significantly reduced. However, forging in the super-beta transus temperature range resulted in remaining anisotropies in the mechanical properties as well as an inferior tensile strength and ductility of the material. It was shown, that by combining L-DED with thermomechanical processing in the sub-beta transus temperature range of Ti6Al4V, a suitable microstructure and desirable mechanical properties for many applications can be obtained, with the advantage of reducing the material waste.
New Frontiers in Materials Design for Laser Additive Manufacturing
Rittinghaus, Silja-Katharina; Jägle, Eric A.; Schmid, Manfred; et al. (2022)
Materials
Dissolution of Zinc Oxide Nanoparticles in the Presence of Slow Acid Generators
Kürsteiner, Ronny; Ritter, Maximilian; Ding, Yong; et al. (2022)
Materials
We describe a preliminary investigation of the dissolution dynamics of zinc oxide nano-particles in the presence of cyclic esters (δ-gluconolactone and propanesultone) as slow acid gener-ators. The particles dissolution is monitored by means of turbidimetry and correlated with the evo-lution of pH over time. The results could be of interest for the design of chemically programmable colloidal systems.
Performance-Based Design of Ferronickel Slag Alkali-Activated Concrete for High Thermal Load Applications
Arce, Andres; Komkova, Anastasija; Papanicolaou, Catherine G.; et al. (2024)
Materials
This study aimed to develop optimized alkali-activated concrete using ferronickel slag for high-temperature applications, focusing on minimizing environmental impact while maintaining high compressive strength and slump. A response surface methodology, specifically the mixture design of experiments, was employed to optimize five components: water, FNS-based alkali-activated binder, and three aggregate sizes. Twenty concrete mixes were tested for slump and compressive strength before and after exposure to 600 degrees C for two hours. The optimal mix achieved 88 MPa compressive strength before heat exposure and 34 MPa after, with a slump of 140 mm. An upscaled version with improved workability (210 mm slump) maintained similar unheated strength but showed reduced post-heating strength (23.5 MPa). Replacing limestone with olivine aggregates in the upscaled mix resulted in 65 MPa unheated and 32 MPa post-heating strengths. Life Cycle Analysis revealed that the optimized ferronickel slag alkali-activated concrete's CO2 emissions were 77% lower than those of ordinary Portland cement concrete of equivalent strength. This approach demonstrated the applicability of mixture design of experiments as an alternative design methodology for alkali activated concrete, providing a valuable performance-based design tool to advance the application of alkali-activated concrete in the construction industry, where no prescriptive standards for alkali-activated ferronickel concrete mix design exist. The study concluded that the developed ferronickel slag alkali-activated concrete, obtained through a performance-based mixture design methodology, offers a promising, environmentally friendly alternative for high-strength, high-temperature applications in construction.
Enhancing High-Alloy Steel Cutting with Abrasive Water Injection Jet (AWIJ) Technology: An Approach Using the Response Surface Methodology (RSM)
Perec, Andrzej; Kawecka, Elzbieta; Pude, Frank (2024)
Materials
The common machining technologies for difficult-to-machine materials do not remarkably ensure acceptable efficiency and precision in bulk materials cutting. High-energy abrasive water injection jet (AWIJ) treatment can cut diverse materials, even multi-layer composites characterized by divergent properties, accurately cutting complex profiles and carrying them out in special circumstances, such as underwater locations or explosion hazard areas. This work reports research on the AWIJ machining quality performance of X22CrMoV12-1 high-alloy steel. The response surface method (RSM) was utilized in modeling. The most influencing process control parameters on cut kerf surface roughness—abrasive flow rate, pressure, and traverse speed—were tested. The result is a mathematical model of the process in the form of a three-variable polynomial. The key control parameter affecting the cut slot roughness turned out to be the traverse speed. In contrast, pressure has a less significant effect, and the abrasive mass flow rate has the slightest impact on the cut slot roughness. Under the optimal conditions determined as a result of the tests, the roughness of the intersection surface Sq does not exceed 2.3 μm. Based on the ANOVA, we confirmed that the model fits over 96% appropriately with the research outcomes. This method reduces the computations and sharply determines the optimum set of control parameters.
Structure–Property Relationships in Shape Memory Metallic Glass Composites
Şopu, Daniel; Yuan, Xudong; Moitzi, Franco; et al. (2019)
Materials
Metallic glass composites with shape memory crystals show enhanced plasticity and work-hardening capability. We investigate the influence of various critical structural aspects such as, the density of crystalline precipitates, their distribution and size, and the structural features and intrinsic properties of the phase on the deformation behavior of metallic amorphous Cu_64 Zr_36 composites with B2 CuZr inclusions using molecular dynamics simulations. We find that a low density of small B2 inclusions with spacing smaller than the critical shear band length controls the formation and distribution of plastic zones in the composite and hinders the formation of critical shear bands. When the free path for shearing allows the formation of mature shear bands a high volume fraction of large B2 precipitates is necessary to stabilize the shear flow and avoid runaway instability. Additionally, we also investigate the deformation mechanism of composites with pure copper crystals for comparison, in order to understand the superior mechanical properties of metallic glass composites with shape memory crystals in more detail. The complex and competing mechanisms of deformation occurring in shape memory metallic glass composites allow this class of materials to sustain large tensile deformation, even though only a low-volume fraction of crystalline inclusions is present.

Publications 1 - 10 of 78

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