Journal: Faraday Discussions

Abbreviation

Faraday Discuss.

Publisher

Royal Society of Chemistry

Journal Volumes

ISSN

1359-6640
1364-5498

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Publications 1 - 10 of 91
  • Applications to water transport systems: general discussion
    Item type: Other Journal Item
    Baaden, Marc; Barboiu, Mihail; Borthakur, Manash Pratim; et al. (2018)
    Faraday Discussions
  • The sensitivities of high-harmonic generation and strong-field ionization to coupled electronic and nuclear dynamics
    Item type: Journal Article
    Baykusheva, Denitsa; Kraus, Peter M.; Zhang, Song Bin; et al. (2014)
    Faraday Discussions
  • Direct hot-carrier transfer in plasmonic catalysis
    Item type: Journal Article
    Kumar, Priyank V.; Rossi, Tuomas P.; Kuisma, Mikael; et al. (2019)
    Faraday Discussions
  • Hydrogenation of ethylene over palladium: Evolution of the catalyst structure by operando synchrotron-based techniques
    Item type: Journal Article
    Bugaev, Aram L.; Usoltsev, Oleg A.; Guda, Alexander A.; et al. (2021)
    Faraday Discussions
    Palladium-based catalysts are exploited on an industrial scale for the selective hydrogenation of hydrocarbons. The formation of palladium carbide and hydride phases under reaction conditions changes the catalytic properties of the material, which points to the importance of operando characterization for determining the relation between the relative fractions of the two phases and the catalyst performance. We present a combined time-resolved characterization by X-ray absorption spectroscopy (in both near-edge and extended regions) and X-ray diffraction of a working palladium-based catalyst during the hydrogenation of ethylene in a wide range of partial pressures of ethylene and hydrogen. Synergistic coupling of multiple techniques allowed us to follow the structural evolution of the palladium lattice as well as the transitions between the metallic, hydride and carbide phases of palladium. The nanometric dimensions of the particles resulted in the considerable contribution of both surface and bulk carbides to the X-ray absorption spectra. During the reaction, palladium carbide is formed, which does not lead to a loss of activity. Unusual contraction of the unit cell parameter of the palladium lattice in the spent catalyst was observed upon increasing hydrogen partial pressure.
  • Attosecond processes and X-ray spectroscopy: general discussion
    Item type: Other Conference Item
    Milne, Chris J.; Weber, Peter M.; Kowalewski, Markus; et al. (2016)
    Faraday Discussions ~ Ultrafast Imaging of Photochemical Dynamics
  • Stochastic and low-scaling techniques/extended systems: general discussion
    Item type: Other Journal Item
    Alavi, Ali; Atalar, Kemal; Berkelbach, Timothy C.; et al. (2024)
    Faraday Discussions
  • A low-energy chilled ammonia process exploiting controlled solid formation for post-combustion CO2 capture
    Item type: Journal Article
    Sutter, Daniel; Gazzani, Matteo; Mazzotti, Marco (2016)
    Faraday Discussions
  • Modelling the stochastic behaviour of primary nucleation
    Item type: Journal Article
    Maggioni, Giovanni; Mazzotti, Marco (2015)
    Faraday Discussions
  • Precipitation of α L-glutamic acid: determination of growth kinetics
    Item type: Journal Article
    Schöll, Jochen; Lindenberg, Christian; Vicum, Lars; et al. (2007)
    Faraday Discussions
    Growth kinetics of α L-glutamic acid was determined based on seeded batch desupersaturation experiments. The growth rate correlation applied in this study accurately describes the growth process in a temperature range of 25–45 °C and in a supersaturation range of 1–3. The newly developed approach for the growth rate characterization has the advantage of a high robustness especially with respect to the influence of competing particle formation mechanisms as nucleation or agglomeration. The efficient technique employs in situ process analytical technologies, e.g. attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and focused beam reflectance measurement (FBRM), different ex situ analytical tools and population balance modeling combined with a non-linear least squares optimization algorithm to determine the growth kinetics. The growth mechanism was identified to be integration controlled and of birth and spread (B + S) type. The quality of the determined growth rate correlation was assessed by comparison with the experimental data and with literature data.
  • Fundamentals: General discussion
    Item type: Other Journal Item
    Althorpe, Stuart C.; Beniwal, Vijay; Bolhuis, Peter G.; et al. (2016)
    Faraday Discussions
Publications 1 - 10 of 91