Journal: Catalysis Letters

Abbreviation

Catal. letters

Publisher

Springer

Journal Volumes

ISSN

1011-372X
1572-879X

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Publications 1 - 10 of 27
  • Synthesis of Efficient TMS@MOF-5 Catalysts for Oxygen Evolution Reaction
    Item type: Journal Article
    Fiaz, Muhammad; Kashif, Muhammad; Fatima, Misal; et al. (2020)
    Catalysis Letters
    For environment friendly water splitting, development of highly efficient and stable oxygen evolution reaction (OER) catalyst composed of earth abundant elements is very challenging. Herein, highly efficient OER catalysts TMS@MOF-5 have been prepared by in-situ incorporation of pre-synthesized various transition metal sulfide (TMS = MnS, FeS, CoS, NiS, CuS and ZnS) nanoparticles into MOF-5. Structure, morphology and composition of prepared samples have been analyzed by powder X-ray diffraction, Fourier Transform Infrared Spectroscopy, Raman Spectroscopy, Scanning Electron Microscopy, Energy Dispersive X-ray Spectroscopy, Elemental Mapping and Ultraviolet–Visible Spectroscopy. OER activity of all these samples was determined by coating them on Ni-foam to form TMS@MOF-5/NF as working electrode through cyclic voltammetry. Among all the samples, NiS@MOF-5/NF exhibited excellent stability and OER catalytic activity as it required just 174 mV overpotential to achieve the 10mAcm−2current density, which is better than many other 3d transition metal based and Ni-based OER catalysts. Present study provides new way to design more efficient Ni-based catalysts for electrochemical water splitting applications.
  • Mechanism of the hydrodenitrogenation of neopentylamine and adamantylamine on sulfided NiMo/Al2O3
    Item type: Journal Article
    Zhao, Y.; Sivasankar, N.; Czyzniewska, J.; et al. (2006)
    Catalysis Letters
  • Heck Reactions of Aryl Chlorides Catalyzed by Ligand Free Palladium Salts
    Item type: Journal Article
    Kleist, Wolfgang; Pröckl, Sandra S.; Köhler, Klaus (2008)
    Catalysis Letters
  • Gold-Catalyzed Aerobic Oxidation of Benzyl Alcohol: Effect of Gold Particle Size on Activity and Selectivity in Different Solvents
    Item type: Journal Article
    Haider, Peter; Kimmerle, Bertram; Krumeich, Frank; et al. (2008)
    Catalysis Letters
  • Metal Phosphides
    Item type: Review Article
    Prins, Roel; Bussell, Mark E. (2012)
    Catalysis Letters
  • The mechanism of N2O decomposition on Fe-ZSM-5
    Item type: Journal Article
    Pirngruber, Gerhard D.; Roy, Pijus K. (2004)
    Catalysis Letters
  • Flame-made alumina supported Pd-Pt nanoparticles: Structural properties and catalytic behavior in methane combustion
    Item type: Journal Article
    Strobel, Reto; Grunwaldt, Jan-Dierk; Camenzind, Adrian; et al. (2005)
    Catalysis Letters
  • Heterogeneous Catalysis Experiments at XFELs. Are we Close to Producing a Catalysis Movie?
    Item type: Journal Article
    Sá, Jacinto; Szlachetko, Jakub (2014)
    Catalysis Letters
    The advent of X-ray free electron lasers enabled scientist to achieve the goal of producing a movie of a catalytic transformation. This perspective highlights the technical developments both on facilities and X-ray spectroscopy that brought us a bit closer to attain the main goal. However there are a couple of issues that need to be solve, namely sample stability and selective triggering.
  • Formylation with "supercritical" CO2
    Item type: Journal Article
    Schmid, Leo; Schneider, Michael S.; Engel, Dominique; et al. (2003)
    Catalysis Letters
  • Surface Organometallic Chemistry: Paving the Way Beyond Well-Defined Supported Organometallics and Single-Site Catalysis
    Item type: Journal Article
    Copéret, Christophe; Fedorov, Alexey; Zhizhko, Pavel A. (2017)
    Catalysis Letters
    The molecular approach to single-site and nanoparticle-based heterogeneous catalysts relies on a stringent control over the surface chemistry, enabled by the judicious choice of dehydroxylated supports and tailored organometallic precursors. Aided by the advanced characterization methods, the field of surface organometallic chemistry (SOMC) has provided molecular-level insights into the mechanism and the nature of active sites of various industrial catalysts. The development of SOMC over the last decades yielded supported catalysts outperforming their homogeneous precursors and provided design principles for catalyst development. Applying the rational structure-activity approach of homogeneous catalysis to the surface species leads to further advances of SOMC, including functional materials for sustainable chemistry, energy storage and imaging, to mention just a few.
Publications 1 - 10 of 27