Soft Matter

Journal: Soft Matter

Publisher

Royal Society of Chemistry

ISSN

1744-683X
1744-6848

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Publications 1 - 10 of 252

Structural color from pigment-loaded nanostructures
Sai, Tianqi; Froufe-Pérez, Luis S.; Scheffold, Frank; et al. (2023)
Soft Matter
Color can originate from wavelength-dependence in the absorption of pigments or the scattering of nanostructures. While synthetic colors are dominated by the former, vivid structural colors found in nature have inspired much research on the latter. However, many of the most vibrant colors in nature involve the interactions of structure and pigment. Here, we demonstrate that pigment can be exploited to efficiently create bright structural color at wavelengths outside its absorption band. We created pigment-enhanced Bragg reflectors by sequentially spin-coating layers of poly-vinyl alcohol (PVA) and polystyrene (PS) loaded with β-carotene (BC). With only 10 double layers, we achieved a peak reflectance over 0.8 at 550 nm and normal incidence. A pigment-free multilayer made of the same materials would require 25 double layers to achieve the same reflectance. Further, pigment loading suppressed the Bragg reflector's characteristic iridescence. Using numerical simulations, we further show that similar pigment loadings could significantly expand the gamut of non-iridescent colors addressable by photonic glasses.
Effects of confinement on phase separation kinetics and final morphology of whey protein isolate-gellan gum mixtures
Wassen, Sophia; Loren, Niklas; Bemmel, Karlijn van; et al. (2013)
Soft Matter
Tuning disorder in structurally colored bioinspired photonic glasses
Demirörs, Ahmet; Manne, Kalpana; Magkiriadou, Sofia; et al. (2024)
Soft Matter
Colloidal crystals, such as opals, display bright and iridescent colors when assembled from submicron particles. While the brightness and purity of iridescent colors are well suited for ornaments, signaling, and anticounterfeiting, their angle dependence limits the range of their applications. In contrast, colloidal glasses display angle-independent structural color that is tunable by the size and local arrangement of particles. However, the angle-independent color of colloidal photonic glasses usually yields pastel colors that are not vivid due to the disorder in the particle assembly. Here, we report an electrophoretic assembly platform for tuning the level of disorder in the particle system from a colloidal crystal to a colloidal glass. Altering the electric field in our electrophoretic platform allows for deliberate control of the assembly kinetics and thus the level of order in the particle assembly. With the help of microscopy, X-ray scattering, and optical characterization, we show that the photonic properties of the assembled films can be tuned with the applied electric field. Our analyses reveal that angle-independent color with optimum color brightness can be achieved in typical colloidal suspensions when the range of order is at ∼3.2 particle diameters, which is expected at a moderate electric field of ∼15 V mm−1.
Lipid multilayered particles
Gerelli, Yuri; Di Bari, Maria T.; Deriu, Antonio; et al. (2010)
Soft Matter
A universal method for planar lipid bilayer formation by freeze and thaw
Sugihara, K.; Jang, B.; Schneider, M.; et al. (2012)
Soft Matter
Elastic stresses reverse Ostwald ripening
Rosowski, Kathryn A.; Vidal-Henriquez, Estefania; Zwicker, David; et al. (2020)
Soft Matter
When liquid droplets nucleate and grow in a polymer network, compressive stresses can significantly increase their internal pressure, reaching values that far exceed the Laplace pressure. When droplets have grown in a polymer network with a stiffness gradient, droplets in relatively stiff regions of the network tend to dissolve, favoring growth of droplets in softer regions. Here, we show that this elastic ripening can be strong enough to reverse the direction of Ostwald ripening: large droplets can shrink to feed the growth of smaller ones. To numerically model these experiments, we generalize the theory of elastic ripening to account for gradients in solubility alongside gradients in mechanical stiffness.
Impact of aggregate formation on the viscosity of protein solutions
Nicoud, Lucrece; Lattuada, Marco; Yates, Andrew; et al. (2015)
Soft Matter
Gaining knowledge on the stability and viscosity of concentrated therapeutic protein solutions is of great relevance to the pharmaceutical industry. In this work, we borrow key concepts from colloid science to rationalize the impact of aggregate formation on the changes in viscosity of a concentrated monoclonal antibody solution. In particular, we monitor the kinetics of aggregate growth under thermal stress by static and dynamic light scattering, and we follow the rise in solution viscosity by measuring the diffusion coefficient of tracer nanoparticles with dynamic light scattering. Moreover, we characterize aggregate morphology in the frame of the fractal geometry. We show that the curves of the increase in viscosity with time monitored at three different protein concentrations collapse on one single master curve when the reaction profiles are normalized based on an effective volume fraction occupied by the aggregates, which depends on the aggregate size, concentration and morphology. Importantly, we find that the viscosity of an aggregate sample is lower than the viscosity of a monomeric sample of a similar occupied volume fraction due to the polydispersity of the aggregate distribution.
Dynamically shaping the surface of silica colloids
Niggel, Vincent; Hsu, Chiao-Peng; Isa, Lucio (2022)
Soft Matter
Surface roughness is an important design parameter to influence the processing of particle-based materials. Current methods to synthesize rough particles present some limitations, e.g. low yield, relative methodological complexity, requirements of multiple steps, or poor roughness control. Here, we thoroughly investigate a facile synthesis route where two silanes, tetraethyl orthosilicate (TEOS) and vinyltrimethoxysilane (VTMS), are added in one pot to form silica particles with controlled corrugated surfaces. We first show that the morphology of these particles can be defined by regulating the amount and ratio of the two silane precursors and by adjusting the concentration of ammonia during synthesis. We characterize the surface topography of the particles using atomic force microscopy and show a direct correlation between surface roughness and the synthesis conditions. Furthermore, we carry out an in situ observation of the evolution of surface morphology and propose a mechanism for surface structuring that hinges on the formation of silane droplets, followed by the preferential hydrolysis/condensation reaction of VTMS starting from the droplet surface and evolving towards the center. The exchange of liquid from the droplets through the VTMS shell leads to stress accumulation and wrinkling/buckling of the particles. Moreover, we explicitly show that osmotic imbalances between the inside and the outside of the droplets regulate their shrinking. We therefore demonstrate that exchanging solvents has a comparable impact to adjusting silane and ammonia content in defining the particle shape and that this synthesis route is highly dynamical. Finally, we demonstrate that it is possible to incorporate fluorescent dyes during synthesis to enable future studies on the impact of surface roughness on dynamic processes, including shear, via direct high-resolution imaging. Our findings show that the mechanism for wrinkling and buckling in colloidal silica particles follows a general scheme found in a broad range of systems, from liposomes and polymeric capsules to Pickering emulsion droplets.
Dynamic stabilisation during the drainage of thin film polymer solutions
Chatzigiannakis, Emmanouil; Vermant, Jan (2021)
Soft Matter
The drainage and rupture of polymer solutions was investigated using a dynamic thin film balance. The polymeric nature of the dissolved molecules leads to significant resistance to the deformation of the thin liquid films. The influence of concentration, molecular weight, and molecular weight distribution of the dissolved polymer on the lifetime of the films was systematically examined for varying hydrodynamic conditions. Depending on the value of the capillary number and the degree of confinement, different stabilisation mechanisms were observed. For low capillary numbers, the lifetime of the films was the highest for the highly concentrated, narrowly-distributed, low molecular weight polymers. In contrast, at high capillary numbers, the flow-induced concentration differences in the film resulted in lateral osmotic stresses, which caused a dynamic stabilisation of the films and the dependency on molecular weight distribution in particular becomes important. Phenomena such as cyclic dimple formation, vortices, and dimple recoil were observed, the occurrence of which depended on the relative magnitude of the lateral osmotic and the hydrodynamic stresses. The factors which lead to enhanced lifetime of the films as a consequence of these flow instabilities can be used to either stabilise foams or, conversely, prevent foam formation.
Poly(acrylamide) films at the solvent-induced glass transition
Li, Ang; Ramakrishna, Shivaprakash N.; Kooij, E. Stefan; et al. (2012)
Soft Matter

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Journal: Soft Matter

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