Solid State Ionics

Journal: Solid State Ionics

Abbreviation

Solid State Ionics

Publisher

Elsevier

ISSN

0167-2738

Show all metadata

Search Results

Publications1 - 10 of 23

Microstructures and electrical conductivity of nanocrystalline ceria-based thin films
Rupp, Jennifer L.M.; Gauckler, Ludwig J. (2006)
Solid State Ionics
An investigation of the oxygen reduction reaction mechanism of La(0.6)Sr(0.4)Co(0.2)Fe(0.8)O(3) using patterned thin films
Simrick, N.J.; Bieberle-Hutter, A.; Ryll, T.M.; et al. (2012)
Solid State Ionics
Electrical and electrochemical characterization of microstructured thin film La1-xSrxCoO3 electrodes
Bieberle-Hütter, Anja; Sogaard, Martin; Tuller, Harry L. (2006)
Solid State Ionics
Trade-off between lithium diffusivity and transference in solid ternary polymer ionic liquid electrolytes
Weijers, Mark; Karanth, Pranav; Homann, Gerrit; et al. (2025)
Solid State Ionics
For battery architectures that need a solid ion conductor with good contacting performance and high stability against electrochemical oxidation, polymerized ionic liquids (PIL) pose a valuable class of materials. The low conductivity of the binary PIL/ lithium salt system can be increased using a ternary ionic liquid acting as plasticiser. The conductive mechanism of the ternary system is however not fully understood. This work shows the shift in conduction mechanism for the ternary Li−/[1,3]PYR-/PDADMA-FSI system by increasing the lithium salt concentration and comparing the transfer mechanism to binary ionic liquid (IL) electrolyte analogues using pulsed field gradient (PFG) nuclear magnetic resonance (NMR), NMR relaxometry, Raman spectroscopy and electrochemical techniques. Two conducting regimes were found which show a strong trade-off between conductivity and transference number. In the low lithium salt regime (≤35 wt% LiFSI), cluster diffusion of aggregated lithium is the dominating mechanism leading to low transference numbers (0.04–0.15 at room temperature (RT)). The high salt regime (≥50 wt% LiFSI) shows diffusion through free lithium ion hopping transfer, which has a stronger dependence on temperature and yields higher transference numbers (0.31 at RT). Increasing lithium salt concentration shows an inverse linear correlation with conductivity. The electrochemical characteristics of ternary IL/PIL/lithium salt are shown to be highly tuneable by varying the lithium salt fraction, while it maintains excellent characteristics like processability, stability and mechanical function.
Improved stability of La0.5Sr0.5FeO3 by Ta-doping for oxygen separation membrane application
Diethelm, S.; Bayraktar, D.; Graule, T.; et al. (2009)
Solid State Ionics
Conduction behavior of Pr1-xSxMn1-yInYO3-delta perovskites
Richter, J.; Holtappels, P.; Vogt, U.; et al. (2006)
Solid State Ionics
Micro-fabrication of patterned LSCF thin-film cathodes with gold current collectors
Simrick, N.J.; Kilner, J.A.; Atkinson, A.; et al. (2011)
Solid State Ionics
Electrical conductivity of the proton conductor BaZr0.9Y0.1O3−δ obtained by high temperature annealing
Duval, Sophie B.C.; Holtappels, Peter; Vogt, Ulrich F.; et al. (2007)
Solid State Ionics
The influence of a high temperature annealing (∼ 2200 °C) on the microstructure and the electrical properties of BaZr0.9Y0.1O3−δ has been examined. The high temperature annealing was achieved using an optical floating zone furnace. The obtained sample is homogeneous with an average grain size of about 5 μm. No additional phases were found in the XRD pattern and the structure was identified to be cubic. After the high temperature annealing, the grain boundary conductivity is increased by approximately two orders of magnitude, while the bulk conductivity remains the same.
Thermodynamic modeling of the ZrO2-YO1.5 system
Chen, Ming; Hallstedt, Bengt; Gauckler, Ludwig J. (2004)
Solid State Ionics
Solid oxide fuel cells with electrolytes prepared via spray pyrolysis
Perednis, D.; Gauckler, L.J. (2004)
Solid State Ionics

Publications1 - 10 of 23

Journal: Solid State Ionics

Abbreviation

Publisher

Journal Volumes

ISSN

Description

Filters

Search Results