Journal: Inorganic Chemistry

Abbreviation

Inorg. Chem.

Publisher

American Chemical Society

Journal Volumes

ISSN

0020-1669
1520-510X

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Publications 1 - 10 of 122
  • The Mystery of the AuIn 1:1 Phase and Its Incommensurate Structural Variations
    Item type: Journal Article
    Folkers, Laura C.; Simonov, Arkadiy; Wang, Fei; et al. (2018)
    Inorganic Chemistry
    In this communication, the AuIn 1:1 phase ( Naturwissenschaften, 1953, 40, 437, DOI: 10.1007/BF00590353), and its ordering behavior at various temperatures is investigated. To enable the growth of a X-ray suitable specimen, a tempering routine was established by the interpretation of a differential scanning calorimetry (DSC) study. In this way, good quality single crystals were grown and measured at the Crystal beamline at Synchrotron SOLEIL. From the acquired data, three variations of this structure could be found at temperatures of 400 °C and 300 °C and room temperature, with differing degrees of incommensurate modulation. Diffuse scattering found at 400 °C was interpreted with the help of a three-dimensional difference pair distribution function (3D-ΔPDF) study.
  • Crystal Structure and Electronic Properties of Y3AlC3
    Item type: Journal Article
    Kotyrba, Martin R.; Cuervo-Reyes, Eduardo; Nesper, Reinhard (2015)
    Inorganic Chemistry
  • Hydrogen Absorption in Transition Metal Silicides
    Item type: Journal Article
    Tokaychuk, Yaroslav O.; Filinchuk, Yaroslav E.; Sheptyakov, Denis V.; et al. (2008)
    Inorganic Chemistry
  • 7Li PGSE Diffusion Measurements on LiPPh2
    Item type: Journal Article
    Fernández, Ignacio; Martínez-Viviente, Eloísa; Pregosin, Paul S. (2004)
    Inorganic Chemistry
  • Single-Site Iridium Picolinamide Catalyst Immobilized onto Silica for the Hydrogenation of CO2 and the Dehydrogenation of Formic Acid
    Item type: Journal Article
    Tensi, Leonardo; Yakimov, Alexander V.; Trotta, Caterina; et al. (2022)
    Inorganic Chemistry
    The development of an efficient heterogeneous catalyst for storing H-2 into CO(2 )and releasing it from the produced formic acid, when needed, is a crucial target for overcoming some intrinsic criticalities of green hydrogen exploitation, such as high flammability, low density, and handling. Herein, we report an efficient heterogeneous catalyst for both reactions prepared by immobilizing a molecular iridium organometallic catalyst onto a high-surface mesoporous silica, through a sol-gel methodology. The presence of tailored single-metal catalytic sites, derived by a suitable choice of ligands with desired steric and electronic characteristics, in combination with optimized support features, makes the immobilized catalyst highly active. Furthermore, the information derived from multinuclear DNP-enhanced NMR spectroscopy, elemental analysis, and Ir L-3-edge XAS indicates the formation of cationic iridium sites. It is quite remarkable to note that the immobilized catalyst shows essentially the same catalytic activity as its molecular analogue in the hydrogenation of CO2. In the reverse reaction of HCOOH dehydrogenation, it is approximately twice less active but has no induction period.
  • Synthesis and crystal structure of lithium beryllium deuteride Li2BeD4
    Item type: Journal Article
    Bulychev,Boris M.; Shpanchenko, Roman V.; Antipov, Evgeny V.; et al. (2004)
    Inorganic Chemistry
  • Decaborane Thiols as Building Blocks for Self-Assembled Monolayers on Metal Surfaces
    Item type: Journal Article
    Bould, Jonathan; Machacek, Jan; Londesborough, Michael G. S.; et al. (2012)
    Inorganic Chemistry
  • Isoreticular Metal–Organic Frameworks Pillared by Monovalent Anions
    Item type: Journal Article
    Bresciani , Giulio; Guiotto , Virginia; Canossa, Stefano; et al. (2025)
    Inorganic Chemistry
    Three isoreticular anion pillared metal–organic frameworks were synthesized using CuX2(X = BF4–, ClO4–, NO3–) salts and the 1,1′-(2-(trifluoromethyl)-1,4-phenylene)bis(1H-imidazole) ligand (bibCF3). Single-crystal X-ray diffraction reveals that these peculiar materials, of the general formula [Cu(bibCF3)2X]·X, feature bidentate monovalent anions acting as pillars between square layers designed by metal ions and organic linkers and extraframework anions located in the channel-like pores. The materials display remarkable thermal and chemical stability and promising CO2adsorption performance, dependent on the nature of the anion.
  • A Unifying Structural and Electronic Concept for Hmd and [FeFe] Hydrogenase Active Sites
    Item type: Journal Article
    Stiebritz, Martin T.; Reiher, Markus (2010)
    Inorganic Chemistry
  • Perovskite-Structure TIMnO3
    Item type: Journal Article
    Yi, Wei; Kumagai, Yu; Spaldin, Nicola; et al. (2014)
    Inorganic Chemistry
Publications 1 - 10 of 122