Efstratios Mitridis

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Mitridis

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Efstratios

ORCID

0000-0002-0748-1471

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Publications 1 - 6 of 6

The role of shadowed droplets in condensation heat transfer
Memos, George; Kokkoris, George; Constantoudis, Vassilios; et al. (2022)
International Journal of Heat and Mass Transfer
Dropwise condensation (DWC) is a phenomenon of common occurrence and significant utility in nature and technology. In energy applications, sustenance of DWC and avoidance of transition to film formation is directly related to efficient heat removal, ensuring high performance of related devices and processes. The efficiency of heat transfer in DWC depends on the heat transfer rates of individual droplets and the droplet size distribution. While the former can be summarily captured in engineering analysis through thermal resistance modeling, the theoretical analysis of the droplet size distribution involves assumptions often oversimplifying the complexity of droplet interactions, especially in the important sub–10 μm regime. Here, a modeling framework based on the thermal resistance approach is coupled with a dynamic model of droplet interactions: Droplet growth, coalescence, jumping, and removal of condensate due to gravity are all present during the unfolding of the phenomenon to accurately predict the droplet size distribution. The motivation is condensation experiments on superhydrophobic surfaces, namely rough aluminum substrates with a hydrophobic coating. Through the “interaction” of computations with measurements, the experimental findings are explained and critical parameters for condensation heat transfer on superhydrophobic surfaces are illuminated. Although larger droplets can be easily observed in experiments, it is shown that large droplets do not significantly affect heat transfer after reaching such state of growth. Instead, it is the small (with radius < 10 μm) and what we term “shadowed” droplets, i.e., the droplets grown in the shadow of the vertical projection area of the larger droplets, that play an important role in the heat transfer process. Due to the growth of these droplets and their concomitant shadowed coalescence and ensuing re-nucleation, the shift in the droplet size distribution towards smaller sizes is significant-enough to render the heat transfer rate rather insensitive to the presence of large droplets. In this regime, the effect of contact angle hysteresis on heat transfer is not crucial. Through the comparison with measurements, the dominant role of the density of nucleation sites on heat transfer is revealed and an estimation of the density of sites (∼105 mm−2) as a function of subcooling is extracted. Finally, the distribution of sites is found critical for heat transfer; an ordered distribution of sites outperforms random and clustered distributions.
Metasurfaces Leveraging Solar Energy for Icephobicity
Mitridis, Efstratios; Schutzius, Thomas M.; Sicher, Alba; et al. (2018)
ACS Nano
Ultrathin Durable Organic Hydrophobic Coatings Enhancing Dropwise Condensation Heat Transfer
Tripathy, Abinash; Regulagadda, Kartik; Lam, Cheuk Wing Edmond; et al. (2022)
Langmuir
Organic hydrophobic layers targeting sustained dropwise condensation are highly desirable but suffer from poor chemical and mechanical stability, combined with low thermal conductivity. The requirement of such layers to remain ultrathin to minimize their inherent thermal resistance competes against durability considerations. Here, we investigate the long-term durability and enhanced heat-transfer performance of perfluorodecanethiol (PFDT) coatings compared to alternative organic coatings, namely, perfluorodecyltriethoxysilane (PFDTS) and perfluorodecyl acrylate (PFDA), the latter fabricated with initiated chemical vapor deposition (iCVD), in condensation heat transfer and under the challenging operating conditions of intense flow (up to 9 m s$^{-1}$) of superheated steam (111 °C) at high pressures (1.42 bar). We find that the thiol coating clearly outperforms the silane coating in terms of both heat transfer and durability. In addition, despite being only a monolayer, it clearly also outperforms the iCVD-fabricated PFDA coating in terms of durability. Remarkably, the thiol layer exhibited dropwise condensation for at least 63 h (>2× times more than the PFDA coating, which survived for 30 h), without any visible deterioration, showcasing its hydrolytic stability. The cost of thiol functionalization per area was also the lowest as compared to all of the other surface hydrophobic treatments used in this study, thus making it the most efficient option for practical applications on copper substrates.
Transparent metasurfaces harvesting sunlight for icephobicity, antifogging and water repellency applications
Mitridis, Efstratios (2019)
Transparent Photothermal Metasurfaces Amplifying Superhydrophobicity by Absorbing Sunlight
Mitridis, Efstratios; Lambley, Henry; Tröber, Sven; et al. (2020)
ACS Nano
Imparting and maintaining surface superhydrophobicity has been receiving significant research attention over the last several years, driven by a broad range of important applications and enabled by advancements in materials and surface nanoengineering. Researchers have investigated the effect of temperature on droplet–surface interactions, which poses additional challenges when liquid nucleation manifests itself, due to ensuing condensation into the surface texture that compromises its antiwetting behavior. Maintaining surface transparency at the same time poses an additional and significant challenge. Often, the solutions proposed are limited by working temperatures or are detrimental to visibility through the surface. Here we introduce a scalable method employing plasmonic photothermal metasurface composites, able to harvest sunlight and naturally heat the surface, sustaining water repellency and transparency under challenging environmental conditions where condensation and fogging would otherwise be strongly promoted. We demonstrate that these surfaces, when illuminated by sunlight, can prevent impalement of impacting water droplets, even when the droplet to surface temperature difference is 50 °C, by suppressing condensate formation within the texture, maintaining transparency. We also show how the same transparent metasurface coating could be combined and work collaboratively with hierarchical micro- and nanorough textures, resulting in simultaneous superior pressure-driven impalement resistance and avoidance of water nucleation and related possible frosting in supercooled conditions. Our work can find a host of applications as a sustainable solution against impacting water on surfaces such as windows, eyewear, and optical components.
Transparent Metasurfaces Counteracting Fogging by Harnessing Sunlight
Walker, Christopher; Mitridis, Efstratios; Kreiner, Thomas; et al. (2019)
Nano Letters

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Efstratios Mitridis

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