Felix Marxer

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Marxer

First Name

Felix

ORCID

0000-0003-1797-6598

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Publications 1 - 7 of 7

Fluids as primary carriers of sulphur and copper in magmatic assimilation
Virtanen, Ville J.; Heinonen, Jussi S.; Molnár, Ferenc; et al. (2021)
Nature Communications
Magmas readily react with their wall-rocks forming metamorphic contact aureoles. Sulphur and possibly metal mobilization within these contact aureoles is essential in the formation of economic magmatic sulphide deposits. We performed heating and partial melting experiments on a black shale sample from the Paleoproterozoic Virginia Formation, which is the main source of sulphur for the world-class Cu-Ni sulphide deposits of the 1.1 Ga Duluth Complex, Minnesota. These experiments show that an autochthonous devolatilization fluid effectively mobilizes carbon, sulphur, and copper in the black shale within subsolidus conditions (≤ 700 °C). Further mobilization occurs when the black shale melts and droplets of Cu-rich sulphide melt and pyrrhotite form at ∼1000 °C. The sulphide droplets attach to bubbles of devolatilization fluid, which promotes buoyancy-driven transportation in silicate melt. Our study shows that devolatilization fluids can supply large proportions of sulphur and copper in mafic–ultramafic layered intrusion-hosted Cu-Ni sulphide deposits.
Polybaric fractional crystallisation of arc magmas - an experimental study
Marxer, Felix (2021)
Alkaline magmas in shallow arc plutonic roots: a field and experimental investigation of hydrous cumulate melting in the southern Adamello batholith
Pimenta Silva, Manuel; Marxer, Felix; Keller, Tobias; et al. (2023)
Contributions to Mineralogy and Petrology
Despite the first-order importance of crystallisation–differentiation for arc magma evolution, several other processes contribute to their compositional diversity. Among them is the remelting of partly crystallised magmas, also known as cumulate melting or ‘petrological cannibalism’. The impact of this process on the plutonic record is poorly constrained. We investigate a nepheline-normative dyke suite close to the Blumone gabbros, a large amphibole-gabbro unit of the Tertiary Southern Alpine Adamello igneous complex. The compositions of the studied dykes are characterised by low SiO2 (43–46 wt. %), MgO (5.0–7.2 wt. %), Ni (18–40 μg/g), and high Al2O3 (20.2–22.0 wt. %) contents. Phenocrystic plagioclase in these dykes exhibits major, trace, and Sr isotope compositions similar to Blumone cumulate plagioclase, suggesting a genetic link between the nepheline-normative dykes and the amphibole-gabbro cumulates. We tested this hypothesis by performing saturation experiments on a nepheline-normative dyke composition in an externally heated pressure vessel at 200 MPa between 975 and 1100 °C at fO2 conditions close to the Ni–NiO buffer. Plagioclase and spinel are near-liquidus phases at and above 1050 °C, contrasting with the typical near-liquidus olivine ± spinel assemblage in hydrous calc-alkaline basalts. The alkaline nature of the dykes results from the abundance of amphibole in the protolith, consistent with melting of amphibole-gabbro cumulates. We modelled the heat budget from the repeated injection of basaltic andesite into a partly crystallised amphibole-gabbro cumulate. The results of this model show that no more than 7% of the cumulate pile reaches temperatures high enough to produce nepheline-normative melts. We propose that such nepheline-normative dykes are a hallmark of hydrous cumulate melting in subvolcanic plumbing systems. Therefore, ne-normative dykes in arc batholiths may indicate periods with high magma fluxes.
Paleobathymetry of Submarine Lavas in the Samail and Troodos Ophiolites: Insights From Volatiles in Glasses and Implications for Hydrothermal Systems
Belgrano, Thomas M.; Tollan, Peter M.; Marxer, Felix; et al. (2021)
Journal of Geophysical Research: Solid Earth
Hydrostatic pressure exerted by the ocean water column fundamentally influences magmatic and hydrothermal processes in submarine volcanic settings and is therefore an important parameter to know when investigating such processes. Currently, there are few reliable methods for reconstructing past ocean depths for ancient volcanic terranes. Here, we develop and test an empirically calibrated statistical approach for determining paleodepths of eruption from the concentrations of H2O and CO2 dissolved in volcanic glasses, utilizing the well-defined pressure-dependent solubility of these volatiles in silicate melts. By comparing newly determined and published glass compositions from the Samail and Troodos ophiolites with sedimentary and fluid inclusion evidence, we propose that the Samail lavas erupted at ocean depths of ∼3.4 km, and the Troodos lavas at ∼4.1 km. These depths are 1–2 km deeper than those assumed in most previous studies of hydrothermal activity in the two ophiolites. These high depths imply high hydrostatic pressures within the underlying oceanic crust. Such pressures may have allowed convecting hydrothermal fluids to attain significantly higher temperatures (e.g., >450°C) than in typical modern ocean ridge hydrothermal systems during metal leaching in the crust and metal precipitation in seafloor sulfide deposits.
A New Albite Microanalytical Reference Material from Piz Beverin for Na, Al and Si Determination, and the Potential for New K-Feldspar Reference Materials
Julien, Allaz; Guillong, Marcel; Tavazzani, Lorenzo; et al. (2023)
Geostandards and Geoanalytical Research
Determination of alkali elements is important to Earth scientists, yet suitable and reliable microanalytical reference materials are lacking. This paper proposes a new albite reference material and evaluates the potential for future K-feldspar reference materials. The proposed Piz Beverin albite reference material from Switzerland yields a homogeneous composition at the centimetre- to micrometre-scale for Si, Al and Na with < 2000 mu g g(-1) total trace elements (mostly heterogeneously distributed Ca, K and Sr). EPMA and LA-ICP-MS measurements confirm a composition of 99.5(2)% albite component, which is supported further by bulk XRF measurements. A round robin evaluation involving nine independent EPMA laboratories confirms its composition and homogeneity for Si, Al and Na. In addition, a set of five distinct clear K-feldspar samples was evaluated as possible reference materials. The first two crystals of adular and orthoclase yield unacceptable inhomogeneities with > 2% relative local variations of Na, K and Ba contents. The three other investigated sets of K-feldspar crystals are yellow sanidine crystals from Itrongay (Madagascar). Despite distinct compositions, EPMA confirms they are each homogeneous at the centimetre to micrometre scale for Si, Al and K and have no apparent inclusions; further investigation to find larger amounts of these materials is therefore justified.
Polybaric fractional crystallisation of arc magmas: an experimental study simulating trans-crustal magmatic systems
Marxer, Felix; Ulmer, Peter; Müntener, Othmar (2022)
Contributions to Mineralogy and Petrology
Crystallisation-driven differentiation is one fundamental mechanism proposed to control the compositional evolution of magmas. In this experimental study, we simulated polybaric fractional crystallisation of mantle-derived arc magmas. Various pressure–temperature trajectories were explored to cover a range of potential magma ascent paths and to investigate the role of decompression on phase equilibria and liquid lines of descent (LLD). Fractional crystallisation was approached in a step-wise manner by repetitively synthesising new starting materials chemically corresponding to liquids formed in previous runs. Experiments were performed at temperatures ranging from 1140 to 870 °C with 30 °C steps, and pressure was varied between 0.8 and 0.2 GPa with 0.2 GPa steps. For most fractionation paths, oxygen fugacity (fO₂) was buffered close to the Ni-NiO equilibrium (NNO). An additional fractionation series was conducted at fO₂ corresponding to the Re-ReO₂ buffer (RRO ≈ NNO+2). High-pressure experiments (0.4–0.8 GPa) were run in piston cylinder apparatus while 0.2 GPa runs were conducted in externally heated pressure vessels. Resulting liquid lines of descent follow calc-alkaline differentiation trends where the onset of pronounced silica enrichment coincides with the saturation of amphibole and/or Fe–Ti–oxide. Both pressure and fO₂ exert crucial control on the stability fields of olivine, pyroxene, amphibole, plagioclase, and Fe–Ti–oxide phases and on the differentiation behaviour of arc magmas. Key observations are a shift of the olivine–clinopyroxene cotectic towards more clinopyroxene-rich liquid composition, an expansion of the plagioclase stability field and a decrease of amphibole stability with decreasing pressure. Decompression-dominated ascent trajectories result in liquid lines of descent approaching the metaluminous compositional range observed for typical arc volcanic rocks, while differentiation trends obtained for cooling-dominated trajectories evolve to peraluminous compositions, similar to isobaric liquid lines of descent at elevated pressures. Experiments buffered at RRO provide a closer match with natural calc-alkaline differentiation trends compared to fO₂ conditions close to NNO. We conclude that decompression-dominated fractionation at oxidising conditions represents one possible scenario for arc magma differentiation.
Ascent-driven differentiation: a mechanism to keep arc magmas metaluminous?
Marxer, Felix; Ulmer, Peter; Müntener, Othmar (2023)
Contributions to Mineralogy and Petrology
Arc magmatism is fundamental to the generation of new continental or island arc crust. However, the mechanisms that add to the chemical complexity of natural calc-alkaline magmas ranging from basaltic to rhyolitic compositions are debated. Differentiation mechanisms currently discussed include magma mixing, assimilation, crustal melting, or (fractional) crystallisation. In this contribution, the differentiation of arc magmas by decompression-driven crystallisation is investigated. We performed a set of equilibrium crystallisation experiments at variable crustal pressures (200–800 MPa) on a hydrous high-Al basalt (3.5 wt.% of H₂O in the starting material) with run temperatures varying from near-liquidus conditions (1110 °C) to 900 °C. Oxygen fugacity was buffered at moderately oxidising conditions close to the NNO equilibrium. Combining these novel experiments with previous polybaric fractional crystallisation experiments (Marxer et al., Contrib Mineral Petrol 177:3, 2022) we demonstrate the effects of pressure on the crystallisation behaviour of calc-alkaline magmas with respect to liquid and cumulate lines of descent, mineral chemistry, and phase proportions. Decompression shifts the olivine-clinopyroxene cotectic curve towards melt compositions with higher normative clinopyroxene and enlarges the stability field of plagioclase. This exerts a key control on the alumina saturation index of residual liquids. We argue that near-adiabatic (or near-isothermal) decompression accompanied by dissolution of clinopyroxene entrained during residual melt extraction in the lower crust keeps arc magmas metaluminous during crystallisation-driven differentiation thereby closely reproducing the compositional spread observed for natural arc rocks.

Publications 1 - 7 of 7

Felix Marxer

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