Alberto Fernando Garrido Castro


Last Name

Garrido Castro

First Name

Alberto Fernando

ORCID

0000-0001-7262-7986

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Publications1 - 1 of 1
  • Scalable Electrochemical Decarboxylative Olefination Driven by Alternating Polarity**
    Item type: Journal Article
    Garrido Castro, Alberto Fernando; Hioki, Yuta; Kusumoto, Yoshifumi; et al. (2023)
    Angewandte Chemie. International Edition
    A mild, scalable (kg) metal-free electrochemical decarboxylation of alkyl carboxylic acids to olefins is disclosed. Numerous applications are presented wherein this transformation can simplify alkene synthesis and provide alternative synthetic access to valuable olefins from simple carboxylic acid feedstocks. This robust method relies on alternating polarity to maintain the quality of the electrode surface and local pH, providing a deeper understanding of the Hofer-Moest process with unprecedented chemoselectivity.
Publications1 - 1 of 1