Guido Panzarasa

Last Name

Panzarasa

First Name

Guido

ORCID

0000-0003-1044-0491

Organisational unit

03917 - Burgert, Ingo / Burgert, Ingo

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Publications 1 - 10 of 47

Formation of Iron (Hydr)Oxide Nanoparticles with a pH-Clock
Kürsteiner, Ronny; Ding, Yong; Ritter, Maximilian; et al. (2022)
Nanomaterials
We demonstrate the autonomous synthesis of iron (hydr)oxide (green rust, magnetite, and lepidocrocite) nanoparticles by precipitating iron(II) ions using hydroxide ions generated in situ with the methylene glycol-sulfite (MGS) reaction, a pH-clock. We show that the nature of the products can be predetermined by tuning the initial iron(II) concentration.
ON/OFF switching of silicon wafer electrochemistry by pH-responsive polymer brushes
Panzarasa, Guido; Dübner, Matthias; Pifferi, Valentina; et al. (2016)
Journal of Materials Chemistry C
pH-Switchable electrochemical properties are demonstrated for the first time for native oxide-coated silicon wafer electrodes. Ultrathin and ultrathick pH-responsive poly(methacrylic acid) (PMAA) brushes, obtained by surface-initiated atom transfer radical polymerization, were used to achieve redox gating. PMAA brushes are reversibly switched between their protonated and deprotonated states by alternating acidic and basic pH, which corresponds to a swelling/collapsing behavior. As a result, the electrochemical properties of the PMAA brush-modified silicon electrode are switched “ON” and “OFF” simply by changing pH. The electrochemical properties of the modified electrode were examined by means of cyclic voltammetry and electrochemical impedance spectroscopy both in the absence and presence of ruthenium(III) hexamine, a well-known cationic redox probe.
Sustainability in Wood Products: A New Perspective for Handling Natural Diversity
Schubert, Mark; Panzarasa, Guido; Burgert, Ingo (2023)
Chemical Reviews
Wood is a renewable resource with excellent qualities and the potential to become a key element of a future bioeconomy. The increasing environmental awareness and drive to achieve sustainability is leading to a resurgence of research on wood materials. Nevertheless, the global climate changes and associated consequences will soon challenge the wood-value chains in several regions (e.g., central Europe). To cope with these challenges, it is necessary to rethink the current practice of wood sourcing and transformation. The goal of this review is to address the intrinsic natural diversity of wood, from its origin to its technological consequences for the present and future manufacturing of wood products. So far, industrial processes have been optimized to repress the variability of wood properties, enabling more efficient processing and production of reliable products. However, the need to preserve biodiversity and the impact of climate change on forests call for new wood processing techniques and green chemistry protocols for wood modification as enabling factors necessary for managing a more diverse wood provision in the future. This article discusses the past developments that have resulted in the current wood value chains and provides a perspective about how natural variability could be turned into an asset for making truly sustainable wood products. After briefly introducing the chemical and structural complexity of wood, the methods conventionally adopted for industrial homogenization and modification of wood are discussed in relation to their evolution toward increased sustainability. Finally, a perspective is given on technological potentials of machine learning techniques and of novel functional wood materials. Here the main message is that through a combination of sustainable forestry, adherence to green chemistry principles and adapted processes based on machine learning, the wood industry could not only overcome current challenges but also thrive in the near future despite the awaiting challenges.
Natural Wood-Based Catalytic Membrane Microreactors for Continuous Hydrogen Generation
Tu, Kunkun; Büchele, Simon; Mitchell, Sharon; et al. (2022)
ACS Applied Materials & Interfaces
The development of controlled processes for continuous hydrogen generation from solid-state storage chemicals such as ammonia borane is central to integrating renewable hydrogen into a clean energy mix. However, to date, most reported platforms operate in batch mode, posing a challenge for controllable hydrogen release, catalyst reusability, and large-scale operation. To address these issues, we developed flow-Through wood-based catalytic microreactors, characterized by inherent natural oriented microchannels. The prepared structured catalysts utilize silver-promoted palladium nanoparticles supported on metal-organic framework (MOF)-coated wood microreactors as the active phase. Catalytic tests demonstrate their highly controllable hydrogen production in continuous mode, and by adjusting the ammonia borane flow and wood species, we reach stable productivities of up to 10.4 cmH23 min-1 cmcat-3. The modular design of the structured catalysts proves readily scalable. Our versatile approach is applicable for other metals and MOF combinations, thus comprising a sustainable and scalable platform for catalytic dehydrogenations and applications in the energy-water nexus.
Passive climate regulation with transpiring wood for buildings with increased energy efficiency
Ding, Yong; Dreimol, Christopher; Zboray, Robert; et al. (2023)
Materials Horizons
Buildings are significant end-users of global energy. About 20% of the energy consumption worldwide is used for maintaining a comfortable indoor climate. Therefore, passive systems for indoor temperature and humidity regulation that can respond to environmental changes are very promising to reduce buildings' energy consumption. We developed a process to improve the responsiveness of wood to humidity changes by laser-drilling microscopic holes and incorporating a hygroscopic salt (calcium chloride). The resulting "transpiring wood" displays superior water adsorption capacity and high moisture exchange rate, allowing regulation of humidity and temperature by the exchange of moisture with the surrounding air. We proved that the hygrothermal performance of transpiring wood can be used to regulate indoor climate, with associated energy savings, for various climate types, thus favoring its application in the building sector. The reduction of temperature fluctuations, thanks to the buffering of temperature peaks, can lead to an indirect energy saving of about 10% for cooling and between 4-27% for heating depending on the climate. Furthermore, our transpiring wood meets different sustainability criteria, from raw materials to the fabrication process, resulting in a product with a low overall environmental impact and that is easy to recycle.
Shaking table investigation of a low-cost and sustainable timber-based energy dissipation system with recentering ability
Tsiavos, Anastasios; Kolyfetis, Dimitrios; Panzarasa, Guido; et al. (2023)
Bulletin of Earthquake Engineering
The aim of this paper is to demonstrate the efficiency of a low-cost and sustainable timber-based energy dissipation system with recentering ability, which can be used as a seismic isolation system or a tuned mass damper for the seismic protection of structures in developing or developed countries. The system, defined as Dovetail with SPrings (Dove-SP), utilizes the attractive properties of timber to store CO2, thus reducing the carbon footprint of the existing energy dissipation systems: It comprises two timber slabs that are designed to slide against each other in a motion that is restrained by a dovetail sliding joint. Two sliding interfaces that allow this sliding motion at an attractively low friction coefficient are experimentally investigated: A PVC sand-wich (PVC-s) sliding interface, comprising a thin layer of sand that is sand-wiched between two PVC layers and a timber sand-wich sliding interface consisting of a thin layer of sand encapsulated between two beech timber surfaces. A set of low-cost steel springs is designed and installed on both sides of the dovetail joint to recenter the structure back to its original position after the end of an earthquake ground motion excitation. A novel, low-cost and deformable wood material fabricated from delignified balsa wood is used to reduce the pounding effects before the activation of the steel springs. The seismic behavior and the recentering ability of the novel timber-based energy dissipation system subjected to an ensemble of recorded earthquake ground motion excitations was experimentally investigated through a large-scale shaking table investigation at ETH Zurich.
Oscillating Reactions Meet Polymers at Interfaces
Osypova, Alina; Dübner, Matthias; Panzarasa, Guido (2020)
Materials
Chemo-mechanical phenomena, including oscillations and peristaltic motions, are widespread in nature—just think of heartbeats—thanks to the ability of living organisms to convert directly chemical energy into mechanical work. Their imitation with artificial systems is still an open challenge. Chemical clocks and oscillators (such as the popular Belousov–Zhabotinsky (BZ) reaction) are reaction networks characterized by the emergence of peculiar spatiotemporal dynamics. Their application to polymers at interfaces (grafted chains, layer-by-layer assemblies, and polymer brushes) offers great opportunities for developing novel smart biomimetic materials. Despite the wide field of potential applications, limited research has been carried out so far. Here, we aim to showcase the state-of-the-art of this fascinating field of investigation, highlighting the potential for future developments and providing a personal outlook.
Functionalized wood with tunable tribopolarity for efficient triboelectric nanogenerators
Sun, Jianguo; Tu, Kunkun; Büchele, Simon; et al. (2021)
Matter
Wood is a state-of-art, renewable, and sustainable building material with excellent mechanical properties but negligible triboelectric polarizability. Strategies to improve and rationally tune the triboelectric properties of wood are needed to further its application for mechanical energy harvesting in smart buildings. We found that wood becomes more triboelectrically positive when modified by in situ-grown zeolitic imidazolate framework-8 (ZIF-8), a metal-organic framework (MOF), and more triboelectrically negative when coated with poly(dimethylsiloxane) (PDMS). A triboelectric nanogenerator (TENG) made with two radial-cut wood samples (L x R x T: 35 x 20 x 1 mm(3)), respectively functionalized with ZIF-8 and PDMS, can generate an open-circuit voltage (Voc) of 24.3 V and a short-circuit current (Isc) of 0.32 mu A upon 50 N, 80 times higher compared with that of native wood. We demonstrate the applicability of our functionalized wood TENG (FW-TENG) in smart buildings by using it to power household lamps, calculators, and electrochromic windows.
Dissolution of Zinc Oxide Nanoparticles in the Presence of Slow Acid Generators
Kürsteiner, Ronny; Ritter, Maximilian; Ding, Yong; et al. (2022)
Materials
We describe a preliminary investigation of the dissolution dynamics of zinc oxide nano-particles in the presence of cyclic esters (δ-gluconolactone and propanesultone) as slow acid gener-ators. The particles dissolution is monitored by means of turbidimetry and correlated with the evo-lution of pH over time. The results could be of interest for the design of chemically programmable colloidal systems.
Chemiluminescent wood
Ritter, Maximilian; Stricker, Laura; Burgert, Ingo; et al. (2024)
Carbohydrate Polymers
Wood materials incorporating new properties are of great interest, especially for advanced applications such as sustainable optics and photonics. In this work we describe a wood functionalization approach, comprising the incorporation of artificial chemiluminescent systems (phenyl oxalate ester‑hydrogen peroxide-fluorophore, and luminol-ferricyanide), resulting in light-emitting wood. By a detailed characterisation of the light emission features we point out the complex interaction between wood scaffold and chemiluminescent systems, especially the quenching effect of wood extractives (for the TCPO-H2O2-fluorophore system) and lignin (for the luminol-ferricyanide system). Moreover, we take advantage of the intrinsic anisotropic porosity and capillarity of wood tissue to study the chemiluminescent front propagation. Our results may inspire the development of novel light-emitting wood materials for a variety of applications, from fundamental studies of water uptake in wood to sensors and even design elements.

Publications 1 - 10 of 47

Guido Panzarasa

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