Thermally Decomposed Binary Fe-Cr Alloys: Toward a Quantitative Relationship Between Strength and Structure
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Date
2022-03
Publication Type
Journal Article
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yes
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Abstract
Binary Fe-Cr alloys are model alloys for ferritic steels proposed as structural materials for future fusion reactors. They are used to investigate the fundamental mechanisms of their degradation induced by heat and irradiation. Fe-Cr presents a miscibility gap, which induces Cr-rich (alpha ') regions in an Fe-rich (alpha) matrix. As this causes embrittlement, it is crucial to understand this phase decomposition and its role, starting with the heat impact. Fe-Cr alloys with 5-40 wt% Cr were annealed at 500 degrees C for up to 1008 h. The microstructure was probed by chemical mapping using scanning transmission electron microscopy with energy-dispersive X-ray spectroscopy (EDS) and atom probe tomography, and hardness was assessed by Vickers testing. Increasing Cr content increases hardness, and beyond 15 wt% Cr it further increases upon annealing. At 20 wt% Cr, nanoscale globular alpha ' precipitates appear, while at 40 wt% Cr an alpha '-percolating structure develops. In both cases, the alpha ' core composition reaches slightly more than 80 at% Cr, and hardness doubles. A unified relationship is found between the alloy strength and the alpha ' structure and it is shown that this type of hardening is a general mechanism for mature systems, independent of the nominal alloy composition.
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published
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Journal / series
Volume
24 (3)
Pages / Article No.
2100909
Publisher
Wiley
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Date collected
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Subject
atom probe tomography; decomposition; Fe–Cr; hardening; phase separation; scanning transmission electron microscopy
Organisational unit
02891 - ScopeM / ScopeM
03661 - Löffler, Jörg F. / Löffler, Jörg F.
Notes
Funding
172934 - Advanced nanoscale characterization of magnetic defects in metals (SNF)