Fibre reinforced PET composite manufacturing via Solid State Polymerisation


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Date

2024-07

Publication Type

Journal Article

ETH Bibliography

yes

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Abstract

Due to the high viscosity of thermoplastics, their processing in fibre-reinforced composite is not trivial. Here we present a route to obviate this issue in a solvent-free manner. To this purpose, we impregnate GF textiles with low-viscosity PET polymer followed by in-situ solid state polymerisation. Processing at low viscosity enables time-efficient manufacturing of void-free intermediate materials, followed by a post-processing step in the solid state that brings back the physical and chemical properties of the polymer. Via this novel approach, PET matrix inside a composite prepreg, was transformed in-situ from an oligomer of few Pa s to a polymer grade with similar Mw to the highest commercially available one, in ≤10 h under mild conditions and in the solid state.

Publication status

published

Editor

Book title

Volume

182

Pages / Article No.

108202

Publisher

Elsevier

Event

Edition / version

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Date created

Subject

Thermoplastic; Prepreg processing; Physical properties; Rheology; Solid state polymerisation

Organisational unit

03507 - Ermanni, Paolo (emeritus) / Ermanni, Paolo (emeritus) check_circle

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