High-pressure flux growth, structural, and superconducting properties of LnFeAsO (Ln = Pr, Nd, Sm) single crystals


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2012-12

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Journal Article

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Abstract

Single crystals of the LnFeAsO (Ln1111, Ln = Pr, Nd, and Sm) family with lateral dimensions up to 1 mm were grown from NaAs and KAs flux at high pressure. The crystals are of good structural quality and become superconducting when O is partially substituted by F (PrFeAsO1-xFx and NdFeAsO1-xFx) or when Fe is substituted by Co (SmFe 1-xCoxAsO). From magnetization measurements, we estimate the temperature dependence and anisotropy of the upper critical field and the critical current density of underdoped PrFeAsO0.7F0.3 crystal with Tc ≈ 25 K. Single crystals of SmFe 1-xCoxAsO with maximal Tc up to 16.3 K for x ≈ 0.08 were grown. From transport and magnetic measurements, we estimate the critical fields and their anisotropy and find these superconducting properties to be quite comparable to the ones in SmFeAsO1-xFx with a much higher Tc ≈ 50 K. The magnetically measured critical current densities are as high as 109 A/m2 at 2 K up to 7 T, with indication of the usual fishtail effect. The upper critical field estimated from resistivity measurements is anisotropic with slopes of ∼-8.7 T/K (H||ab plane) and ∼-1.7 T/K (H||c axis). This anisotropy (∼5) is similar to that in other Ln1111 crystals with various higher Tc's.

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published

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86 (21)

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214509

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American Physical Society

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03569 - Batlogg, Bertram (emeritus) check_circle

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