High Aspect Ratio Nanoscale Pores through BCP-Based Metal Oxide Masks and Advanced Dry Etching
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Date
2023-12-20
Publication Type
Review Article
ETH Bibliography
yes
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Abstract
The reliable and regular modification of the surface properties of substrates plays a crucial role in material research and the development of functional surfaces. A key aspect of this is the development of the surface pores and topographies. These can confer specific advantages such as high surface area as well as specific functions such as hydrophobic properties. Here, we introduce a combination of nanoscale self-assembled block-copolymer-based metal oxide masks with optimized deep reactive ion etching (DRIE) of silicon to permit the fabrication of porous topographies with aspect ratios of up to 50. Following the evaluation of our procedure and involved parameters using various techniques, such as AFM or SEM, the suitability of our features for applications relying on high light absorption as well as efficient thermal management is explored and discussed in further detail.
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published
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Book title
Journal / series
Volume
15 (50)
Pages / Article No.
57960 - 57969
Publisher
American Chemical Society
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Edition / version
Methods
Software
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Date collected
Date created
Subject
block copolymer; metal infiltration; DRIE; high aspect ratio; porous silicon
