Dopant incorporation into garnet solid solutions—a breakdown of Goldschmidt’s first rule
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Date
2003
Publication Type
Journal Article
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yes
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Abstract
Atomistic simulations suggest trace elements are more soluble in a 50∶50 pyrope (Mg3Al2Si3O12)–grossular (Ca3Al2Si3O12) garnet mixture than in either end-member; consistent with partitioning experiments, and, contrary to Goldschmidt’s first rule, large trace element cations may substitute for Mg2+, small trace elements for Ca2+.
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published
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Journal / series
Volume
2003 (6)
Pages / Article No.
786 - 787
Publisher
Royal Society of Chemistry