Hydrogen production by steam-gasification of petroleum coke using concentrated solar power—III. Reactor experimentation with slurry feeding


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Date

2007-06

Publication Type

Journal Article

ETH Bibliography

yes

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Abstract

We report on the experimental evaluation of a 5 kW solar chemical reactor for the steam-gasification of petcoke, carried out in a high-flux solar furnace. A petcoke-water slurry was continuously injected into a solar cavity-receiver to create a vortex flow directly exposed to concentrated solar radiation. For a nominal reactor temperature of 1500 K, a water-petcoke molar ratio of 4.8, and a residence time of 2.4 s, the maximum degree of petcoke conversion was 87%. Typical syngas composition produced was 62% H2, 25% CO, 12% CO2, and 1% CH4. The solar energy conversion efficiency-defined as the portion of solar energy absorbed as chemical energy and sensible heat-attained 17%. The effect of varying the particle size (range 8.5-200 μ m) and slurry stoichiometry (range 2.1-6.3) on the degree of chemical conversion and energy conversion efficiency was examined.

Publication status

published

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Book title

Volume

32 (8)

Pages / Article No.

992 - 996

Publisher

Elsevier

Event

Edition / version

Methods

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Date collected

Date created

Subject

Solar; Gasification; Slurry; Carbonaceous materials; Hydrogen

Organisational unit

03530 - Steinfeld, Aldo (emeritus) / Steinfeld, Aldo (emeritus) check_circle

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