Safe Preparation and Delivery of Graphite Targets for ¹⁴C Analysis: Procedures of Bravho Lab at Bologna University


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Date

2024-10

Publication Type

Conference Paper

ETH Bibliography

yes

Citations

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Data

Abstract

Nowadays, most radiocarbon (¹⁴C) laboratories can reliably avoid and remove any possible sample contamination during the pretreatment of organic samples (e.g., bones, charcoal, or trees) thanks to a series of methods commonly used by the radiocarbon community. However, what about the final step, the storage of graphite? Rarely do the laboratories produce their graphite and ship it as pressed targets to accelerator mass spectrometry (AMS) facilities for measurement. Pressed graphite in aluminum targets are vulnerable to contamination, and during shipment or storage, exogenous carbon can be introduced again. Here we report a test on various archaeological sample materials from different environments and different periods (from the past three millennia to the Middle Paleolithic period). We transformed them into graphite, pressed the graphite into targets and sent them to two different AMS laboratories to be dated. We observe that packing details of the targets, extended shipment and storage time may lead to contamination which can be avoided by appropriate packaging in tight metal cans and sealed in vacuum bags. Close cooperation and coordination between our chemistry laboratory and the AMS facilities, high standards in contamination removal, and efficient measurement planning enabled us to obtain reliable ¹⁴C ages within a short time.

Publication status

published

Editor

Book title

24th Radiocarbon and 10th ¹⁴C & Archaeology, Zurich, Sept. 11–16, 2022 Proceedings Part 1 of 2

Journal / series

Volume

66 (5)

Pages / Article No.

1368 - 1378

Publisher

Cambridge University Press

Event

24th Radiocarbon - 10th ¹⁴C & Archaeology Conference

Edition / version

Methods

Software

Geographic location

Date collected

Date created

Subject

AMS dating; contamination; pretreatment; radiocarbon

Organisational unit

08619 - Labor für Ionenstrahlphysik (LIP) / Laboratory of Ion Beam Physics (LIP) check_circle

Notes

Funding

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