Bisulfate - Cluster based atmospheric pressure chemical ionization mass spectrometer for high-sensitivity (< 100 ppqV) detection of atmospheric dimethyl amine: Proof-of-concept and first ambient data from boreal forest

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Date
2015Type
- Journal Article
Citations
Cited 26 times in
Web of Science
Cited 27 times in
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ETH Bibliography
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Abstract
Atmospheric amines may play a crucial role in formation of new aerosol particles via nucleation with sulfuric acid. Recent studies have revealed that concentrations below 1 pptV can significantly promote nucleation of sulfuric acid particles. While sulfuric acid detection is relatively straightforward, no amine measurements to date have been able to reach the critical sub-pptV concentration range and atmospheric amine concentrations are in general poorly characterized. In this work we present a proof-of-concept of an instrument capable of detecting dimethyl amine (DMA) with concentrations even down to 70 ppqV (parts per quadrillion, 0.07 pptV) for a 15 min integration time. Detection of ammonia and amines other than dimethyl amine is discussed. We also report results from the first ambient measurements performed in spring 2013 at a boreal forest site. While minute signals above the signal-to-noise ratio that could be attributed to trimethyl or propyl amine were observed, DMA concentration never exceeded the detection threshold of ambient measurements (150 ppqV), thereby questioning, though not excluding, the role of DMA in nucleation at this location. Show more
Permanent link
https://doi.org/10.3929/ethz-b-000104857Publication status
publishedExternal links
Journal / series
Atmospheric Measurement TechniquesVolume
Pages / Article No.
Publisher
CopernicusMore
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Citations
Cited 26 times in
Web of Science
Cited 27 times in
Scopus
ETH Bibliography
yes
Altmetrics