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dc.contributor.author
Knop-Gericke, Axel
dc.contributor.author
Kleimenov, Evgueni
dc.contributor.author
Hävecker, Michael
dc.contributor.author
Blume, Raoul
dc.contributor.author
Teschner, Detre
dc.contributor.author
Zafeiratos, Spiros
dc.contributor.author
Schlögl, Robert
dc.contributor.author
Bukhtiyarov, Valerii I.
dc.contributor.author
Kaichev, Vasily V.
dc.contributor.author
Prosvirin, Igor P.
dc.contributor.author
Nizovskii, Alexander I.
dc.contributor.author
Bluhm, Hendrik
dc.contributor.author
Barinov, Alexei
dc.contributor.author
Dudin, Pavel
dc.contributor.author
Kiskinova, Maya
dc.date.accessioned
2023-09-05T12:50:12Z
dc.date.available
2017-06-12T02:17:29Z
dc.date.available
2023-09-05T12:50:12Z
dc.date.issued
2009
dc.identifier.isbn
978-0-12-374336-7
en_US
dc.identifier.issn
0360-0564
dc.identifier.issn
2163-0747
dc.identifier.other
10.1016/S0360-0564(08)00004-7
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/113924
dc.description.abstract
X‐ray photoelectron spectroscopy (XPS) is commonly applied for the characterization of surfaces in ultrahigh vacuum apparatus, but the application of XPS at elevated pressures has been known for more than 35 years. This chapter is a description of the development of XPS as a novel method to characterize surfaces of catalysts under reaction conditions. This technique offers opportunities for determination of correlations between the electronic surface structures of active catalysts and the catalytic activity, which can be characterized simultaneously by analysis of gas‐phase products. Apparatus used for XPS investigations of samples in reactive atmospheres is described here; the application of synchrotron radiation allows the determination of depth profiles in the catalyst, made possible by changes in the photon energy. The methods are illustrated with examples including methanol oxidation on copper and ethene epoxidation on silver. Correlations between the abundance of surface oxygen species and yields of selective oxidation products are presented in detail. Further examples include CO adsorption and methanol decomposition on palladium and CO oxidation on ruthenium.
en_US
dc.language.iso
en
en_US
dc.publisher
Academic Press
en_US
dc.title
X-Ray Photoelectron Spectroscopy for Investigation of Heterogeneous Catalytic Processes
en_US
dc.type
Journal Article
dc.date.published
2009-02-19
ethz.journal.title
Advances in Catalysis
ethz.journal.volume
52
en_US
ethz.journal.abbreviated
Adv. catal.
ethz.pages.start
213
en_US
ethz.pages.end
272
en_US
ethz.identifier.wos
ethz.publication.place
Amsterdam
en_US
ethz.publication.status
published
en_US
ethz.date.deposited
2017-06-12T02:18:03Z
ethz.source
ECIT
ethz.identifier.importid
imp59365431c885e82078
ethz.ecitpid
pub:175670
ethz.eth
yes
en_US
ethz.availability
Metadata only
en_US
ethz.rosetta.installDate
2017-07-14T18:16:23Z
ethz.rosetta.lastUpdated
2024-02-03T03:17:43Z
ethz.rosetta.versionExported
true
ethz.COinS
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