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dc.contributor.author
Liu, Liu
dc.contributor.author
Ruiz, David A.
dc.contributor.author
Dahcheh, Fatme
dc.contributor.author
Bertrand, Guy
dc.contributor.author
Suter, Riccardo
dc.contributor.author
Tondreau, Aaron M.
dc.contributor.author
Grützmacher, Hansjörg
dc.date.accessioned
2019-06-18T15:25:52Z
dc.date.available
2017-06-12T02:29:59Z
dc.date.available
2019-06-18T15:25:52Z
dc.date.issued
2016-03-01
dc.identifier.issn
2041-6520
dc.identifier.issn
2041-6539
dc.identifier.other
10.1039/c5sc04504e
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/114049
dc.identifier.doi
10.3929/ethz-b-000114049
dc.description.abstract
Sodium phosphaethynolate reacts with [MCl(PDI)] (M = Co, Ir; PDI = pyridinediimine) to give metallaphosphaketenes, which in the case of iridium rearranges into a dimetalladiphosphene, via CO migration from phosphorus to the metal. Two different bonding modes of the PCO anion to CAAC-coinage metal complexes [CAAC: cyclic (alkyl)(amino)(carbene)] are reported, one featuring a strong Au–P bond and the other an η2 coordination to copper. The gold complex appears to be mostly unreactive whereas the copper complex readily reacts with various organic substrates. A completely free PCO anion was structurally characterized as the [Cu(La)2]+ (OCP)− salt. It results from the simple displacement of the PCO unit of the cationic (CAAC)Cu(PCO) complex by a second equivalent of CAAC.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Royal Society of Chemistry
en_US
dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
dc.title
Isolation of Au-, Co-η1PCO and Cu-η2PCO complexes, conversion of an Ir-η1PCO complex into a dimetalladiphosphene, and an interaction-free PCO anion
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution 3.0 Unported
dc.date.published
2016-01-04
ethz.journal.title
Chemical Science
ethz.journal.volume
7
en_US
ethz.journal.issue
3
en_US
ethz.journal.abbreviated
Chem. sci.
ethz.pages.start
2335
en_US
ethz.pages.end
2341
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.identifier.nebis
006104946
ethz.publication.place
Cambridge
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
ethz.date.deposited
2017-06-12T02:35:32Z
ethz.source
ECIT
ethz.identifier.importid
imp593654361764b83728
ethz.ecitpid
pub:175819
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2017-07-13T13:55:03Z
ethz.rosetta.lastUpdated
2019-06-18T15:26:04Z
ethz.rosetta.versionExported
true
ethz.COinS
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