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dc.contributor.author
Trincado, Mónica
dc.contributor.author
Sinha, Vivek
dc.contributor.author
Rodriguez-Lugo, Rafael E.
dc.contributor.author
Pribanic, Bruno
dc.contributor.author
de Bruin, Bas
dc.contributor.author
Grützmacher, Hansjörg
dc.date.accessioned
2017-10-17T09:39:53Z
dc.date.available
2017-10-06T02:40:04Z
dc.date.available
2017-10-17T09:39:53Z
dc.date.issued
2017-04-28
dc.identifier.other
10.1038/ncomms14990
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/190972
dc.identifier.doi
10.3929/ethz-b-000190972
dc.description.abstract
Small organic molecules provide a promising solution for the requirement to store large amounts of hydrogen in a future hydrogen-based energy system. Herein, we report that diolefin–ruthenium complexes containing the chemically and redox non-innocent ligand trop 2 dad catalyse the production of H 2 from formaldehyde and water in the presence of a base. The process involves the catalytic conversion to carbonate salt using aqueous solutions and is the fastest reported for acceptorless formalin dehydrogenation to date. A mechanism supported by density functional theory calculations postulates protonation of a ruthenium hydride to form a low-valent active species, the reversible uptake of dihydrogen by the ligand and active participation of both the ligand and the metal in substrate activation and dihy- drogen bond formation.
en_US
dc.language.iso
en
en_US
dc.publisher
Nature Publishing Group
en_US
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
dc.title
Homogeneously catalysed conversion of aqueous formaldehyde to H-2 and carbonate
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution 4.0 International
dc.date.published
2017-04-28
ethz.journal.title
Nature Communications
ethz.journal.volume
8
en_US
ethz.pages.start
14990
en_US
ethz.size
11 p.
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
London
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
ethz.date.deposited
2017-10-06T02:40:05Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2017-10-17T09:39:55Z
ethz.rosetta.lastUpdated
2019-02-02T12:43:13Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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