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dc.contributor.author
Guillong, Marcel
dc.contributor.author
Hametner, Kathrin
dc.contributor.author
Reusser, Eric
dc.contributor.author
Wilson, Stephen A.
dc.contributor.author
Günther, Detlef
dc.date.accessioned
2021-03-15T12:05:44Z
dc.date.available
2018-02-15T12:16:54Z
dc.date.available
2018-03-17T14:12:51Z
dc.date.available
2017-06-09T11:04:34Z
dc.date.available
2018-03-17T14:11:27Z
dc.date.available
2018-03-19T12:19:33Z
dc.date.available
2021-03-15T12:05:44Z
dc.date.issued
2005-11
dc.identifier.issn
1639-4488
dc.identifier.issn
1751-908X
dc.identifier.other
10.1111/j.1751-908x.2005.tb00903.x
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/250928
dc.description.abstract
New glass reference materials GSA‐1G, GSC‐1G, GSD‐1G and GSE‐1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP‐MS, concentrations of fifty‐eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR‐2G was used as a more closely matrix‐matched reference material in order to compare the effect of matrix‐matched and non matrix‐matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix‐matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix‐matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.
en_US
dc.language.iso
en
en_US
dc.publisher
Wiley-Blackwell
en_US
dc.subject
laser ablation-inductively coupled plasma-mass spectrometry
en_US
dc.subject
electron microprobe
en_US
dc.subject
glass reference materials
en_US
dc.subject
NIST SRM 610
en_US
dc.subject
USGS BCR-2G
en_US
dc.subject
microsonde électronique
en_US
dc.subject
matériaux certifiés de référence
en_US
dc.subject
spectrométrie de masse couplée à un plasma induit avec ablation laser
en_US
dc.title
Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths
en_US
dc.type
Journal Article
dc.date.published
2007-05-22
ethz.journal.title
Geostandards and Geoanalytical Research
ethz.journal.volume
29
en_US
ethz.journal.issue
3
en_US
ethz.journal.abbreviated
Geostand. Geoanal. Res
ethz.pages.start
315
en_US
ethz.pages.end
331
en_US
ethz.identifier.wos
ethz.publication.place
Oxford
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03512 - Günther, Detlef / Günther, Detlef
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02330 - Dep. Erdwissenschaften / Dep. of Earth Sciences::02725 - Institut für Geochemie und Petrologie / Institute of Geochemistry and Petrology::03417 - Heinrich, Christoph A. (emeritus) / Heinrich, Christoph A. (emeritus)
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03512 - Günther, Detlef / Günther, Detlef
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02330 - Dep. Erdwissenschaften / Dep. of Earth Sciences::02725 - Institut für Geochemie und Petrologie / Institute of Geochemistry and Petrology::03417 - Heinrich, Christoph A. (emeritus) / Heinrich, Christoph A. (emeritus)
ethz.date.deposited
2017-06-09T11:04:51Z
ethz.source
FORM
ethz.source
ECIT
ethz.identifier.importid
imp59364e08e3e2579161
ethz.ecitpid
pub:56205
ethz.eth
yes
en_US
ethz.availability
Metadata only
en_US
ethz.rosetta.installDate
2018-08-03T05:29:05Z
ethz.rosetta.lastUpdated
2022-03-29T05:46:38Z
ethz.rosetta.versionExported
true
dc.identifier.olduri
http://hdl.handle.net/20.500.11850/241163
dc.identifier.olduri
http://hdl.handle.net/20.500.11850/34979
ethz.COinS
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