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dc.contributor.author
Wang, Long
dc.contributor.author
Kehr, Gerald
dc.contributor.author
Daniliuc, Constantin G.
dc.contributor.author
Brinkkötter, Melanie
dc.contributor.author
Wiegand, Thomas
dc.contributor.author
Wübker, Anna-Lena
dc.contributor.author
Eckert, Hellmut
dc.contributor.author
Liu, Lei
dc.contributor.author
Brandenburg, Jan Gerit
dc.contributor.author
Grimme, Stefan
dc.contributor.author
Erker, Gerhard
dc.date.accessioned
2018-06-21T11:43:25Z
dc.date.available
2018-06-21T04:24:57Z
dc.date.available
2018-06-21T11:43:25Z
dc.date.issued
2018-06-07
dc.identifier.issn
2041-6520
dc.identifier.issn
2041-6539
dc.identifier.other
10.1039/c8sc01089g
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/271158
dc.identifier.doi
10.3929/ethz-b-000271158
dc.description.abstract
In solution the PCy3/B(C6F5)3 pair is rapidly deactivated by nucleophilic aromatic substitution. In the solid state deactivation is effectively suppressed and the active frustrated phosphane/borane Lewis pair splits dihydrogen or adds to sulfur dioxide. A variety of phosphane/B(C6F5)3 pairs have been used to carry out active FLP reactions in the solid state. The reactions were analyzed by DFT calculations and by solid state NMR spectroscopy. The solid state dihydrogen splitting reaction was also carried out under near to ambient conditions with suspensions of the non-quenched phosphane/borane mixtures in the fluorous liquid perfluoromethylcyclohexane.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Royal Society of Chemistry
en_US
dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
dc.title
Solid state frustrated Lewis pair chemistry
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution 3.0 Unported
ethz.journal.title
Chemical Science
ethz.journal.volume
9
en_US
ethz.journal.issue
21
en_US
ethz.journal.abbreviated
Chem. Sci.
ethz.pages.start
4859
en_US
ethz.pages.end
4865
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.publication.place
Cambridge
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03496 - Meier, Beat H. / Meier, Beat H.
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03496 - Meier, Beat H. / Meier, Beat H.
ethz.date.deposited
2018-06-21T04:25:27Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2018-06-21T11:43:28Z
ethz.rosetta.lastUpdated
2020-02-15T13:38:10Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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