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dc.contributor.author
Bernasconi, Stefano M.
dc.contributor.author
Müller, Inigo A.
dc.contributor.author
Bergmann, Kristin
dc.contributor.author
Breitenbach, Sebastian F.M.
dc.contributor.author
Fernandez, Alvaro
dc.contributor.author
Hodell, David A.
dc.contributor.author
Jaggi, Madalina
dc.contributor.author
Meckler, Anna Nele
dc.contributor.author
Millan, Isabel M.
dc.contributor.author
Ziegler, Martin
dc.date.accessioned
2018-11-09T16:14:10Z
dc.date.available
2018-11-09T05:49:39Z
dc.date.available
2018-11-09T16:14:10Z
dc.date.issued
2018-09
dc.identifier.issn
1525-2027
dc.identifier.other
10.1029/2017GC007385
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/302436
dc.identifier.doi
10.3929/ethz-b-000302436
dc.description.abstract
About a decade after its introduction, the field of carbonate clumped isotope thermometry is rapidly expanding because of the large number of possible applications and its potential to solve long‐standing questions in Earth Sciences. Major factors limiting the application of this method are the very high analytical precision required for meaningful interpretations, the relatively complex sample preparation procedures, and the mass spectrometric corrections needed. In this paper we first briefly review the evolution of the analytical and standardization procedures and discuss the major remaining sources of uncertainty. We propose that the use of carbonate standards to project the results to the carbon dioxide equilibrium scale can improve interlaboratory data comparability and help to solve long‐standing discrepancies between laboratories and temperature calibrations. The use of carbonates reduces uncertainties related to gas preparation and cleaning procedures and ensures equal treatment of samples and standards. We present a set of carbonate standards of diverse composition, discuss how they can be used to correct for mass spectrometric biases, and demonstrate that their use significantly improves the comparability among four laboratories. We propose that the use of these standards or of a similar set of carbonate standards will improve the comparability of data across laboratories.
en_US
dc.format
application/pdf
dc.language.iso
en
en_US
dc.publisher
Wiley
en_US
dc.rights.uri
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject
clumped isotopes
en_US
dc.subject
mass spectrometry
en_US
dc.subject
standardization
en_US
dc.subject
carbonate
en_US
dc.subject
paleothermometry
en_US
dc.title
Reducing Uncertainties in Carbonate Clumped Isotope Analysis Through Consistent Carbonate-Based Standardization
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
dc.date.published
2018-08-06
ethz.journal.title
Geochemistry, Geophysics, Geosystems
ethz.journal.volume
19
en_US
ethz.journal.issue
9
en_US
ethz.journal.abbreviated
Geochem. geophys. geosyst.
ethz.pages.start
2895
en_US
ethz.pages.end
2914
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.grant
Clumped Isotope Thermometry in burial diagenetic systems - part 2: new constraints on the kinetics of 13C-18O bond reordering from contact metamorphic aureoles of magmatic intrusions
en_US
ethz.grant
Application of Clumped Isotope Thermometry to burial diagenetic and low temperature hydrothermal systems.
en_US
ethz.grant
Improving the reconstruction of deep-time paleoclimate and diagenetic history of sedimentary basins with carbonate clumped isotopes.
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Hoboken, NJ
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02330 - Dep. Erdwissenschaften / Dep. of Earth Sciences::02704 - Geologisches Institut / Geological Institute::09601 - Stoll, Heather / Stoll, Heather
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02330 - Dep. Erdwissenschaften / Dep. of Earth Sciences::02704 - Geologisches Institut / Geological Institute::09601 - Stoll, Heather / Stoll, Heather
ethz.grant.agreementno
160046
ethz.grant.agreementno
143485
ethz.grant.agreementno
169849
ethz.grant.fundername
SNF
ethz.grant.fundername
SNF
ethz.grant.fundername
SNF
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.program
Projektförderung in Mathematik, Natur- und Ingenieurwissenschaften (Abteilung II)
ethz.grant.program
Projektförderung in Mathematik, Natur- und Ingenieurwissenschaften (Abteilung II)
ethz.grant.program
Projektförderung in Mathematik, Natur- und Ingenieurwissenschaften (Abteilung II)
ethz.date.deposited
2018-11-09T05:49:39Z
ethz.source
SCOPUS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2018-11-09T16:14:33Z
ethz.rosetta.lastUpdated
2021-02-15T02:27:41Z
ethz.rosetta.versionExported
true
ethz.COinS
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