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dc.contributor.author
Cosimi, Elena
dc.contributor.author
Trapp, Nils
dc.contributor.author
Ebert, Marc-Olivier
dc.contributor.author
Wennemers, Helma
dc.date.accessioned
2019-03-27T12:26:07Z
dc.date.available
2019-01-22T10:53:54Z
dc.date.available
2019-02-01T11:12:48Z
dc.date.available
2019-03-27T12:26:07Z
dc.date.issued
2019-02-25
dc.identifier.issn
1359-7345
dc.identifier.issn
1364-548X
dc.identifier.other
10.1039/C8CC09987A
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/318467
dc.identifier.doi
10.3929/ethz-b-000318467
dc.description.abstract
A combined experimental and computational approach provided insight into the nature and conformational dependence of long-range 4JHF couplings in α-fluoro amides. The dependence of 4JHF on substituents and the solvent was investigated. H–F coupling constants determined by NMR spectroscopy are in agreement with DFT calculations. NBO analysis revealed that a favourable nF→σNH* interaction correlates with the magnitude of 4JHF.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Royal Society of Chemistry
en_US
dc.rights.uri
http://creativecommons.org/licenses/by-nc/3.0/
dc.title
Combined experimental and theoretical study of long-range H-F interactions in α-fluoro amides
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial 3.0 Unported
dc.date.published
2019-01-16
ethz.journal.title
Chemical Communications
ethz.journal.volume
55
en_US
ethz.journal.issue
16
en_US
ethz.journal.abbreviated
Chem. commun.
ethz.pages.start
2253
en_US
ethz.pages.end
2256
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Cambridge
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::08663 - NMR-Service LOC
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::03940 - Wennemers, Helma / Wennemers, Helma
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02024 - Small Molecule Crystallography Center
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02024 - Small Molecule Crystallography Center
ethz.date.deposited
2019-01-22T10:54:06Z
ethz.source
FORM
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2019-03-27T12:26:30Z
ethz.rosetta.lastUpdated
2019-03-27T12:26:30Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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