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dc.contributor.author
Yang, Xiuxiu
dc.contributor.author
Gianetti, Thomas L.
dc.contributor.author
Wörle, Michael
dc.contributor.author
van Leest, Nicolaas P.
dc.contributor.author
de Bruin, Bas
dc.contributor.author
Grützmacher, Hansjörg
dc.date.accessioned
2019-02-20T11:39:35Z
dc.date.available
2019-02-13T10:43:19Z
dc.date.available
2019-02-20T11:39:35Z
dc.date.issued
2019-01
dc.identifier.issn
2041-6520
dc.identifier.issn
2041-6539
dc.identifier.other
10.1039/c8sc02864h
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/324866
dc.identifier.doi
10.3929/ethz-b-000324866
dc.description.abstract
The dinuclear ruthenium complex [Ru2H(μ-H)(Me2dad)(dbcot)2] contains a 1,4-dimethyl-diazabuta-1,3-diene (Me2dad) as a non-innocent bridging ligand between the metal centers to give a [Ru2(Me2dad)] core. In addition, each ruthenium is bound to one dibenzo[a,e]cyclooctatetraene (dbcot) ligand. This Ru dimer converts H2 to protons and electrons. It also catalyzes reversibly under mild conditions the selective hydrogenation of vitamins K2 and K3 to their corresponding hydroquinone equivalents without affecting the C=C double bonds. Mechanistic studies suggest that the [Ru2(Me2dad)] moiety, like hydrogenases, reacts with H2 and releases electrons and protons stepwise.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Royal Society of Chemistry
en_US
dc.rights.uri
http://creativecommons.org/licenses/by-nc/3.0/
dc.title
A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial 3.0 Unported
dc.date.published
2018-11-15
ethz.journal.title
Chemical Science
ethz.journal.volume
10
en_US
ethz.journal.issue
4
en_US
ethz.journal.abbreviated
Chem. Sci.
ethz.pages.start
1117
en_US
ethz.pages.end
1125
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.publication.place
Cambridge
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02024 - Small Molecule Crystallography Center
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02024 - Small Molecule Crystallography Center
ethz.date.deposited
2019-02-13T10:43:20Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2019-02-20T11:39:51Z
ethz.rosetta.lastUpdated
2021-02-15T03:40:29Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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