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dc.contributor.author
Signorell, Ruth
dc.date.accessioned
2020-02-04T10:19:46Z
dc.date.available
2020-02-04T09:50:56Z
dc.date.available
2020-02-04T10:16:13Z
dc.date.available
2020-02-04T10:18:15Z
dc.date.available
2020-02-04T10:19:46Z
dc.date.issued
2020-01-19
dc.identifier.uri
http://hdl.handle.net/20.500.11850/396879
dc.identifier.doi
10.3929/ethz-b-000396879
dc.description.abstract
In a recent article, David Bartels addresses the issue of the band shape of the genuine binding energy spectrum of the hydrated electron. He essentially claims that the genuine binding energy of the hydrated electron must be Gaussian in shape independent of the photon energy used for ionization, contrary to what was found in our previous work for excitations energies in the UV (3.6-5.8 eV photon energy). Further, he alleges that the asymmetric (bimodal) distribution found for the genuine binding energy in our previous work must have resulted from deficiencies in the scattering cross sections used in the scattering calculations. Bartels concludes that these deficiencies arise from an allegedly wrong value of -1.0eV for the escape barrier used in the original fitting procedure to determine the scattering cross section. In the following, we show that these claims are unfounded and based on partly incorrect assumptions.
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dc.format
application/pdf
en_US
dc.language.iso
en
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dc.publisher
ETH Zurich
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dc.rights.uri
http://rightsstatements.org/page/InC-NC/1.0/
dc.title
Comment on: Is the Hydrated Electron Vertical Detachment Genuinely Bimodal? J. Phys. Chem. Lett. 2019, 10, 4910-4913
en_US
dc.type
Working Paper
dc.rights.license
In Copyright - Non-Commercial Use Permitted
ethz.size
4 p.
en_US
ethz.notes
arxiv:2001.06915 [physics.chem-ph]
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ethz.publication.place
Zurich
en_US
ethz.publication.status
published
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ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
ethz.date.deposited
2020-02-04T09:51:04Z
ethz.source
FORM
ethz.eth
yes
en_US
ethz.availability
Open access
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ethz.rosetta.installDate
2020-02-04T10:16:23Z
ethz.rosetta.lastUpdated
2020-02-15T23:59:53Z
ethz.rosetta.versionExported
true
ethz.COinS
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