Show simple item record

dc.contributor.author
Signorell, Ruth
dc.date.accessioned
2020-02-04T12:20:40Z
dc.date.available
2020-02-04T10:44:30Z
dc.date.available
2020-02-04T12:20:40Z
dc.date.issued
2020-01-23
dc.identifier.uri
http://hdl.handle.net/20.500.11850/396911
dc.identifier.doi
10.3929/ethz-b-000396911
dc.description.abstract
Two recent articles present results that allegedly exclude a possible multimodal distribution of the hydrated electron in ultraviolet photoelectron spectra. The first article bases its conclusion on the assumption that the non-Gaussian genuine band shape previously retrieved for the solvated electron in liquid water is an artefact arising from insufficient electron scattering cross sections used in the retrieval. The second article excludes a multimodal band shape based on a photoelectron spectrum of the solvated electron in water clusters recorded at a single ultraviolet photon energy, and it further assumes that cluster results are transferable to the liquid without further justification. Here, we show that based on current data multimodal distributions cannot be unambiguously excluded. Furthermore, the transferability of cluster results to the liquid can neither be justified nor refuted on the basis of currently available experimental ultraviolet photoelectron spectra.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
ETH Zurich
en_US
dc.rights.uri
http://rightsstatements.org/page/InC-NC/1.0/
dc.title
Can current experimental data exclude non-Gaussian genuine band shapes in ultraviolet photoelectron spectra of the hydrated electron?
en_US
dc.type
Working Paper
dc.rights.license
In Copyright - Non-Commercial Use Permitted
ethz.size
9 p.
en_US
ethz.notes
arXiv:2001.08413 [physics.chem-ph]
en_US
ethz.publication.place
Zurich
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
ethz.relation.isPreviousVersionOf
10.3929/ethz-b-000400620
ethz.date.deposited
2020-02-04T10:44:38Z
ethz.source
FORM
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2020-02-04T12:20:51Z
ethz.rosetta.lastUpdated
2020-02-16T00:00:15Z
ethz.rosetta.versionExported
true
ethz.COinS
ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.atitle=Can%20current%20experimental%20data%20exclude%20non-Gaussian%20genuine%20band%20shapes%20in%20ultraviolet%20photoelectron%20spectra%20of%20the%20hydrated%20electron?&rft.date=2020-01-23&rft.au=Signorell,%20Ruth&rft.genre=preprint&rft.btitle=Can%20current%20experimental%20data%20exclude%20non-Gaussian%20genuine%20band%20shapes%20in%20ultraviolet%20photoelectron%20spectra%20of%20the%20hydrated%20electron?
 Search print copy at ETH Library

Files in this item

Thumbnail

Publication type

Show simple item record