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dc.contributor.author
Glatzel, Thilo
dc.contributor.author
Zimmerli, Lars
dc.contributor.author
Kawai, Shigeki
dc.contributor.author
Meyer, Ernst
dc.contributor.author
Fendt, Leslie-Anne
dc.contributor.author
Diederich, François
dc.date.accessioned
2019-08-29T10:47:39Z
dc.date.available
2017-06-09T13:44:05Z
dc.date.available
2019-08-29T10:42:01Z
dc.date.available
2019-08-29T10:47:39Z
dc.date.issued
2011-01-13
dc.identifier.issn
2190-4286
dc.identifier.other
10.3762/bjnano.2.4
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/39774
dc.identifier.doi
10.3929/ethz-b-000039774
dc.description.abstract
The growth of molecular assemblies at room temperature on insulating surfaces is one of the main goals in the field of molecular electronics. Recently, the directed growth of porphyrin-based molecular wires on KBr(001) was presented. The molecule–surface interaction associated with a strong dipole moment of the molecules was sufficient to bind them to the surface; while a stabilization of the molecular assemblies was reached due to the intermolecular interaction by π–π binding. Here, we show that the atomic structure of the substrate can control the direction of the wires and consequently, complex molecular assemblies can be formed. The electronic decoupling of the molecules by one or two monolayers of KBr from the Cu(111) substrate is found to be insufficient to enable comparable growth conditions to bulk ionic materials.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Beilstein-Institut zur Förderung der Chemischen Wissenschaften
en_US
dc.rights.uri
http://creativecommons.org/licenses/by/2.0/
dc.subject
Directed growth
en_US
dc.subject
KBr
en_US
dc.subject
Molecular wires
en_US
dc.subject
NaCI
en_US
dc.subject
nc-AFM
en_US
dc.subject
Porphyrin
en_US
dc.subject
Self assembly
en_US
dc.title
Oriented growth of porphyrin-based molecular wires on ionic crystals analysed by nc-AFM
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution 2.0 Generic
ethz.journal.title
Beilstein Journal of Nanotechnology
ethz.journal.volume
2
en_US
ethz.journal.abbreviated
Beilstein j. nanotechnol.
ethz.pages.start
34
en_US
ethz.pages.end
39
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.publication.place
Frankfurt am Main
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::03344 - Diederich, François (emeritus)
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::03344 - Diederich, François (emeritus)
ethz.date.deposited
2017-06-09T13:44:09Z
ethz.source
ECIT
ethz.identifier.importid
imp59364e693756438985
ethz.ecitpid
pub:64243
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2017-07-14T15:31:00Z
ethz.rosetta.lastUpdated
2019-08-29T10:47:54Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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