From CO or CO2?: space-resolved insights into high-pressure CO2 hydrogenation to methanol over Cu/ZnO/Al2O3
dc.contributor.author
Gaikwad, Rohit
dc.contributor.author
Reymond, Helena
dc.contributor.author
Phongprueksathat, Nat
dc.contributor.author
Rudolf von Rohr, Philipp
dc.contributor.author
Urakawa, Atsushi
dc.date.accessioned
2021-08-05T06:07:29Z
dc.date.available
2020-06-03T18:13:08Z
dc.date.available
2020-06-04T13:46:56Z
dc.date.available
2021-08-05T06:07:29Z
dc.date.issued
2020-05-07
dc.identifier.issn
2044-4753
dc.identifier.issn
2044-4761
dc.identifier.other
10.1039/d0cy00050g
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/418013
dc.identifier.doi
10.3929/ethz-b-000418013
dc.description.abstract
The reaction pathway of high-pressure CO2 hydrogenation over a Cu/ZnO/Al2O3 catalyst is investigated through the gradients of reactants/products concentration and catalyst temperature within the catalytic reactor. This study reveals that methanol is formed through direct CO2 hydrogenation at low temperature, while above 260 °C methanol formation is mediated via CO which is formed by reverse water–gas shift reaction.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Royal Society of Chemistry
en_US
dc.rights.uri
http://creativecommons.org/licenses/by-nc/3.0/
dc.title
From CO or CO2?: space-resolved insights into high-pressure CO2 hydrogenation to methanol over Cu/ZnO/Al2O3
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial 3.0 Unported
dc.date.published
2020-03-05
ethz.journal.title
Catalysis Science & Technology
ethz.journal.volume
10
en_US
ethz.journal.issue
9
en_US
ethz.journal.abbreviated
Catal. Sci. Technol.
ethz.pages.start
2763
en_US
ethz.pages.end
2768
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.grant
Carbon Dioxide Hydrogenation: New Synthetic Perspectives for Chemical Energy Carriers
en_US
ethz.grant
Tailored CO2 Hydrogenation Catalysts for Selective Methanol Synthesis via Structure-Activity Relationship across Time and Length Scale
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Cambridge
en_US
ethz.publication.status
published
en_US
ethz.grant.agreementno
154448
ethz.grant.agreementno
183495
ethz.grant.fundername
SNF
ethz.grant.fundername
SNF
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.program
Sinergia
ethz.grant.program
Sinergia
ethz.date.deposited
2020-06-03T18:13:12Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2020-06-04T13:47:06Z
ethz.rosetta.lastUpdated
2023-02-06T22:19:14Z
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true
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