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dc.contributor.author
Dechambre, Dominique
dc.contributor.author
Wolff, Ludger
dc.contributor.author
Pauls, Christoph
dc.contributor.author
Bardow, André
dc.date.accessioned
2020-07-22T09:12:38Z
dc.date.available
2020-07-20T12:11:03Z
dc.date.available
2020-07-22T09:12:38Z
dc.date.issued
2014-12-17
dc.identifier.issn
1520-5045
dc.identifier.issn
0888-5885
dc.identifier.other
10.1021/ie5035573
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/427387
dc.description.abstract
Measurements of liquid–liquid equilibria (LLE) are characterized by high experimental effort, long equilibration times, high sample consumption, and hence high costs. To reduce these efforts, we analyze LLE measurements using optimal experimental design (OED). Using OED, we identify experiments with the highest information content for LLE systems of both type I and type II. The NRTL and UNIQUAC gE models are employed. The optimal designs are compared to conventional designs. The optimal designs employ very few (3–5) distinct experiments located in regions where the curvature of the binodal curve is high. Thereby, at least half of the experimental effort can be saved without losing either prediction or parameter accuracy.
en_US
dc.language.iso
en
en_US
dc.publisher
American Chemical Society
en_US
dc.title
Optimal Experimental Design for the Characterization of LiquidLiquid Equilibria
en_US
dc.type
Journal Article
dc.date.published
2014-12-05
ethz.journal.title
Industrial & Engineering Chemistry Research
ethz.journal.volume
53
en_US
ethz.journal.issue
50
en_US
ethz.journal.abbreviated
Ind. Eng. Chem. Res.
ethz.pages.start
19620
en_US
ethz.pages.end
19627
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Washington, DC
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02130 - Dep. Maschinenbau und Verfahrenstechnik / Dep. of Mechanical and Process Eng.::02668 - Inst. f. Energie- und Verfahrenstechnik / Inst. Energy and Process Engineering::09696 - Bardow, André / Bardow, André
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02130 - Dep. Maschinenbau und Verfahrenstechnik / Dep. of Mechanical and Process Eng.::02668 - Inst. f. Energie- und Verfahrenstechnik / Inst. Energy and Process Engineering::09696 - Bardow, André / Bardow, André
en_US
ethz.date.deposited
2020-07-20T12:11:11Z
ethz.source
BATCH
ethz.eth
no
en_US
ethz.availability
Metadata only
en_US
ethz.rosetta.installDate
2020-07-22T09:12:50Z
ethz.rosetta.lastUpdated
2022-03-29T02:41:35Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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