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dc.contributor.author
Ban, Loren
dc.contributor.author
West, Christopher W.
dc.contributor.author
Chasovskikh, Egor
dc.contributor.author
Gartmann, Thomas E.
dc.contributor.author
Yoder, Bruce L.
dc.contributor.author
Signorell, Ruth
dc.date.accessioned
2020-10-02T05:23:57Z
dc.date.available
2020-09-08T06:05:07Z
dc.date.available
2020-09-08T09:57:03Z
dc.date.available
2020-10-01T14:32:22Z
dc.date.available
2020-10-02T05:23:57Z
dc.date.issued
2020-10-01
dc.identifier.issn
1089-5639
dc.identifier.issn
1520-5215
dc.identifier.other
10.1021/acs.jpca.0c06935
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/439029
dc.identifier.doi
10.3929/ethz-b-000439029
dc.description.abstract
Below band gap formation of solvated electrons in neutral water clusters using pump-probe photoelectron imaging is compared with recent data for liquid water and with above band gap excitation studies in the liquid and clusters. Similar relaxation times in the order of 200 fs and 1-2 ps are retrieved for below and above band gap excitation, in both clusters and liquid. The relaxation times independence from the generation process indicates that these times are dominated by the solvent response, which is significantly slower than the different solvated electron formation processes. The analysis of the temporal evolution of the vertical electron binding energy and the electron binding energy at half maximum suggests a dependence of the solvation time on the binding energy.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
American Chemical Society
en_US
dc.rights.uri
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject
Photoelectron spectroscopy
en_US
dc.subject
Hydrated electrons
en_US
dc.subject
Electron scattering
en_US
dc.subject
Electron binding energy
en_US
dc.subject
Ultrafast imaging
en_US
dc.title
Below Band Gap Formation of Solvated Electrons in Neutral Water Clusters?
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
dc.date.published
2020-09-02
ethz.journal.title
The Journal of Physical Chemistry A
ethz.journal.volume
124
en_US
ethz.journal.issue
39
en_US
ethz.journal.abbreviated
J. phys. chem., A
ethz.pages.start
7959
en_US
ethz.pages.end
7965
en_US
ethz.size
7 p.
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.grant
Droplet Photoelectron Imaging
en_US
ethz.grant
Phase Transitions of Ultrafine Aerosol Particles: Condensation, Freezing, and Metal Formation in Confined Systems
en_US
ethz.grant
Fellowship Program of the NCCR MUST (National Competence Center for Research in Molecular Ultrafast Science and Technology) and the Cluster of Excellence RESOLV
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Washington, DC
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
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Projekte MINT
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ethz.date.deposited
2020-09-08T06:05:18Z
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