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dc.contributor.author
Breitwieser, Kevin
dc.contributor.author
Chen, Peter
dc.date.accessioned
2021-02-25T09:25:52Z
dc.date.available
2021-02-24T09:51:23Z
dc.date.available
2021-02-25T09:25:52Z
dc.date.issued
2021-02
dc.identifier.other
10.1107/S2056989021000712
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/471294
dc.identifier.doi
10.3929/ethz-b-000471294
dc.description.abstract
The title oxastannaborininol compound, [Sn(C4H9)2(C10H7BO2)], has been synthesized and crystallized. While heterocycles containing a C–O–B group are common, heterocycles containing an E–O–B unit, where E is an element of the carbon group except for carbon, are rare. In fact, while heterocycles containing Si–O–B units are occasionally reported (although without crystal structures), there are no reports for the corresponding germanium, tin or lead analogues. Herein, the first synthesis and crystal structure of a heterocycle containing an Sn–O–B unit is described. The asymmetric unit contains one molecule showing a notable disorder of the tin atom and the butyl groups. They occupy two sets of positions with site-occupancy factors of 0.295 (6) and 0.705 (6).
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
International Union of Crystallography
en_US
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
dc.subject
crystal structure
en_US
dc.subject
boron
en_US
dc.subject
tin
en_US
dc.subject
heterocycle
en_US
dc.subject
stannaborininol
en_US
dc.title
Crystal structure of a 1,1-dibutyl-1H,3H-naphtho[1,8-cd][1,2,6]oxastannaborinin-3-ol
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution 4.0 International
ethz.journal.title
Acta Crystallographica Section E: Crystallographic Communications
ethz.journal.volume
77
en_US
ethz.pages.start
180
en_US
ethz.pages.end
183
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Bethesda, MD
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::03425 - Chen, Peter / Chen, Peter
ethz.date.deposited
2021-02-24T09:51:28Z
ethz.source
SCOPUS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2021-02-25T09:26:03Z
ethz.rosetta.lastUpdated
2021-02-25T09:26:03Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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