Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers
dc.contributor.author
Delcaillau, Tristan
dc.contributor.author
Boehm, Philip
dc.contributor.author
Morandi, Bill
dc.date.accessioned
2021-03-26T07:28:56Z
dc.date.available
2021-03-25T16:27:16Z
dc.date.available
2021-03-26T07:28:56Z
dc.date.issued
2021-03-17
dc.identifier.issn
0002-7863
dc.identifier.issn
1520-5126
dc.identifier.other
10.1021/jacs.1c00529
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/476419
dc.identifier.doi
10.3929/ethz-b-000476419
dc.description.abstract
We describe a new functional group metathesis between aryl nitriles and aryl thioethers. The catalytic system nickel/dcype is essential to achieve this fully reversible transformation in good to excellent yields. Furthermore, the cyanide- and thiol-free reaction shows high functional group tolerance and great efficiency for the late-stage derivatization of commercial molecules. Finally, synthetic applications demonstrate its versatility and utility in multistep synthesis.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
American Chemical Society
en_US
dc.rights.uri
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.title
Nickel-Catalyzed Reversible Functional Group Metathesis between Aryl Nitriles and Aryl Thioethers
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
dc.date.published
2021-03-03
ethz.journal.title
Journal of the American Chemical Society
ethz.journal.volume
143
en_US
ethz.journal.issue
10
en_US
ethz.journal.abbreviated
J. Am. Chem. Soc.
ethz.pages.start
3723
en_US
ethz.pages.end
3728
en_US
ethz.size
6 p.
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.grant
Catalytic synthesis of unprotected amines and heterocycles
en_US
ethz.grant
Shuttle Catalysis for Reversible Molecular Construction
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Washington, DC
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::09634 - Morandi, Bill / Morandi, Bill
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::09634 - Morandi, Bill / Morandi, Bill
en_US
ethz.grant.agreementno
184658
ethz.grant.agreementno
757608
ethz.grant.fundername
SNF
ethz.grant.fundername
EC
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.funderDoi
10.13039/501100000780
ethz.grant.program
H2020
ethz.grant.program
Projekte MINT
ethz.date.deposited
2021-03-25T16:27:23Z
ethz.source
FORM
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2021-03-26T07:29:14Z
ethz.rosetta.lastUpdated
2022-03-29T06:00:42Z
ethz.rosetta.versionExported
true
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