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dc.contributor.author
Mundra, Shishir
dc.contributor.author
Provis, John L.
dc.date.accessioned
2021-07-05T12:57:58Z
dc.date.available
2021-06-21T10:10:34Z
dc.date.available
2021-06-21T11:41:26Z
dc.date.available
2021-07-05T12:57:58Z
dc.date.issued
2021-09
dc.identifier.issn
0022-2461
dc.identifier.issn
1573-4803
dc.identifier.other
10.1007/s10853-021-06237-x
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/490567
dc.identifier.doi
10.3929/ethz-b-000490567
dc.description.abstract
The pore fluid within many concretes is highly alkaline and rich in reduced sulfur species, but the influence of such alkaline-sulfide solutions on the surface film formed on steel reinforcement is poorly understood. This study investigates the critical role of HS− in defining mild steel passivation chemistry. The surface film formed on the steel in alkaline-sulfide solutions contains Fe(OH)2 and Fe–S complexes, and the critical chloride concentration to induce corrosion increases at high sulfide concentration. However, this behavior is dependent on the duration of exposure of the steel to the electrolyte, and the nature of the sulfidic surface layer.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Springer
en_US
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
dc.title
Mechanisms of passivation and chloride-induced corrosion of mild steel in sulfide-containing alkaline solutions
en_US
dc.type
Journal Article
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution 4.0 International
dc.date.published
2021-06-16
ethz.journal.title
Journal of Materials Science
ethz.journal.volume
56
en_US
ethz.journal.issue
26
en_US
ethz.journal.abbreviated
J. Mater. Sci.
ethz.pages.start
14783
en_US
ethz.pages.end
14802
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Norwell
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02115 - Dep. Bau, Umwelt und Geomatik / Dep. of Civil, Env. and Geomatic Eng.::02606 - Institut für Baustoffe (IfB) / Institute for Building Materials::09593 - Angst, Ueli / Angst, Ueli
en_US
ethz.identifier.orcidWorkCode
95597843
ethz.date.deposited
2021-06-21T10:10:42Z
ethz.source
FORM
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2021-07-05T12:58:05Z
ethz.rosetta.lastUpdated
2021-07-05T12:58:05Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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