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dc.contributor.author
Rivero Crespo, Miguel Ángel
dc.contributor.author
Toupalas, Georgios
dc.contributor.author
Morandi, Bill
dc.date.accessioned
2022-02-07T11:57:50Z
dc.date.available
2021-12-25T03:52:49Z
dc.date.available
2022-01-25T16:05:26Z
dc.date.available
2022-02-07T11:57:50Z
dc.date.issued
2021-12-22
dc.identifier.issn
0002-7863
dc.identifier.issn
1520-5126
dc.identifier.other
10.1021/jacs.1c09884
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/522308
dc.identifier.doi
10.3929/ethz-b-000522308
dc.description.abstract
Porous organic materials (polymers and COFs) have shown a number of promising properties; however, the lability of their linkages often limits their robustness and can hamper downstream industrial application. Inspired by the outstanding chemical, mechanical, and thermal resistance of the 1D polymer poly(phenylene sulfide) (PPS), we have designed a new family of porous poly(aryl thioether)s, synthesized via a mild Pd-catalyzed C-S/C-S metathesis-based method, that merges the attractive features common to porous polymers and PPS in a single material. In addition, the method is highly modular, allowing to easily introduce application-oriented functionalities in the materials for a series of environmentally relevant applications including metal capture, metal sensing, and heterogeneous catalysis. Moreover, despite their extreme chemical resistance, the polymers can be easily recycled to recover the original monomers, offering an attractive perspective for their sustainable use. In a broader context, these results clearly demonstrate the untapped potential of emerging single-bond metathesis reactions in the preparation of new, recyclable materials.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
American Chemical Society
en_US
dc.rights.uri
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.title
Preparation of Recyclable and Versatile Porous Poly(aryl thioether)s by Reversible Pd-Catalyzed C-S/C-S Metathesis
en_US
dc.type
Journal Article
dc.rights.license
Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International
dc.date.published
2021-12-06
ethz.journal.title
Journal of the American Chemical Society
ethz.journal.volume
143
en_US
ethz.journal.issue
50
en_US
ethz.journal.abbreviated
J. Am. Chem. Soc.
ethz.pages.start
21331
en_US
ethz.pages.end
21339
en_US
ethz.version.deposit
publishedVersion
en_US
ethz.grant
Shuttle Catalysis for Reversible Molecular Construction
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Washington, DC
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::09634 - Morandi, Bill / Morandi, Bill
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::09634 - Morandi, Bill / Morandi, Bill
ethz.grant.agreementno
757608
ethz.grant.fundername
EC
ethz.grant.funderDoi
10.13039/501100000780
ethz.grant.program
H2020
ethz.date.deposited
2021-12-25T03:53:04Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Open access
en_US
ethz.rosetta.installDate
2022-02-07T11:57:56Z
ethz.rosetta.lastUpdated
2022-03-29T18:40:15Z
ethz.rosetta.versionExported
true
ethz.COinS
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