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dc.contributor.author
Schnitzer, Tobias
dc.contributor.author
Paenurk, Eno
dc.contributor.author
Trapp, Nils
dc.contributor.author
Gershoni-Poranne, Renana
dc.contributor.author
Wennemers, Helma
dc.date.accessioned
2022-01-31T08:33:53Z
dc.date.available
2022-01-17T09:08:41Z
dc.date.available
2022-01-31T08:33:53Z
dc.date.issued
2021-01-20
dc.identifier.issn
0002-7863
dc.identifier.issn
1520-5126
dc.identifier.other
10.1021/jacs.0c11793
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/526117
dc.description.abstract
Despite impressive advances in the construction of metal–organic frameworks (MOFs), the formation of networks from peptidic ligands is difficult, though they are sought after for their modularity and biocompatibility. Herein we present a peptide–metal framework that consists of helical oligoproline ligands and Zn/K (or Zn/Rb). The crystalline network contains pleated nanosheets with the metal ions aligned in strings. This unprecedented architecture derives from under-appreciated London dispersion interactions between the oligoproline ligands that play in concert with the metal coordination to create the network. Hence, the secondary structure of the peptidic ligand represents an additional control element for the creation of new MOF architectures. We anticipate that our results will instruct the design of further peptidic MOFs and enable the generation of versatile biocompatible materials.
en_US
dc.language.iso
en
en_US
dc.publisher
American Chemical Society
en_US
dc.title
Peptide–Metal Frameworks with Metal Strings Guided by Dispersion Interactions
en_US
dc.type
Journal Article
dc.date.published
2021-01-08
ethz.journal.title
Journal of the American Chemical Society
ethz.journal.volume
143
en_US
ethz.journal.issue
2
en_US
ethz.journal.abbreviated
J. Am. Chem. Soc.
ethz.pages.start
644
en_US
ethz.pages.end
648
en_US
ethz.grant
Bioinspirierte Asymmetrische Katalyse (Fortsetzung)
en_US
ethz.publication.place
Washington, DC
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::03940 - Wennemers, Helma / Wennemers, Helma
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02024 - Small Molecule Crystallography Center
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02024 - Small Molecule Crystallography Center
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02514 - Laboratorium für Organische Chemie / Laboratory of Organic Chemistry::03940 - Wennemers, Helma / Wennemers, Helma
en_US
ethz.grant.agreementno
169423
ethz.grant.fundername
SNF
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.program
Projekte MINT
ethz.date.deposited
2022-01-17T09:08:47Z
ethz.source
FORM
ethz.eth
yes
en_US
ethz.availability
Metadata only
en_US
ethz.rosetta.installDate
2022-01-31T08:34:17Z
ethz.rosetta.lastUpdated
2022-03-29T18:24:31Z
ethz.rosetta.versionExported
true
ethz.COinS
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