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dc.contributor.author
Niman, John W.
dc.contributor.author
Kamerin, Benjamin S.
dc.contributor.author
Kresin, Vitaly V.
dc.contributor.author
Krohn, Jan
dc.contributor.author
Signorell, Ruth
dc.contributor.author
Halonen, Roope
dc.contributor.author
Hansen, Klavs
dc.date.accessioned
2022-10-25T05:47:55Z
dc.date.available
2022-03-05T14:49:32Z
dc.date.available
2022-06-22T11:40:33Z
dc.date.available
2022-10-24T13:21:49Z
dc.date.available
2022-10-25T05:47:55Z
dc.date.issued
2022-03-07
dc.identifier.issn
1463-9084
dc.identifier.issn
1463-9076
dc.identifier.other
10.1039/d1cp05866e
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/535494
dc.identifier.doi
10.3929/ethz-b-000535494
dc.description.abstract
Abundance spectra of (CO2)N clusters up to N ≈ 500 acquired under a wide range of adiabatic expansion conditions are analyzed within the evaporative ensemble framework. The analysis reveals that the cluster stability functions display a strikingly universal pattern for all expansion conditions. These patterns reflect the inherent properties of individual clusters. From this analysis the size-dependent cluster binding energies are determined, shell and subshell closing sizes are identified, and cuboctahedral packing ordering for sizes above N ≈ 130 is confirmed. It is demonstrated that a few percent variation in the dissociation energies translates into significant abundance variations, especially for the larger clusters.
en_US
dc.format
application/pdf
en_US
dc.language.iso
en
en_US
dc.publisher
Royal Society of Chemistry
en_US
dc.title
Shells in CO2 clusters
en_US
dc.type
Journal Article
dc.date.published
2022-02-14
ethz.journal.title
Physical Chemistry Chemical Physics
ethz.journal.volume
24
en_US
ethz.journal.issue
9
en_US
ethz.journal.abbreviated
Phys. Chem. Chem. Phys.
ethz.pages.start
5343
en_US
ethz.pages.end
5350
en_US
ethz.size
40 p. accepted version
en_US
ethz.version.deposit
acceptedVersion
en_US
ethz.grant
How weak intermolecular interactions govern the formation and properties of clusters and aerosol droplets
en_US
ethz.identifier.wos
ethz.identifier.scopus
ethz.publication.place
Cambridge
en_US
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02515 - Laboratorium für Physikalische Chemie / Laboratory of Physical Chemistry::03961 - Signorell, Ruth / Signorell, Ruth
en_US
ethz.grant.agreementno
200306
ethz.grant.fundername
SNF
ethz.grant.funderDoi
10.13039/501100001711
ethz.grant.program
Projekte MINT
ethz.date.deposited
2022-03-05T14:50:18Z
ethz.source
WOS
ethz.eth
yes
en_US
ethz.availability
Embargoed
en_US
ethz.date.embargoend
2023-02-14
ethz.rosetta.installDate
2022-06-22T11:40:41Z
ethz.rosetta.lastUpdated
2022-06-22T11:40:41Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
ethz.COinS
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