Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Trisphosphines Combining Phosphorus, Planar, and Carbon Chirality
dc.contributor.author
Barbaro, Pierluigi
dc.contributor.author
Bianchini, Claudio
dc.contributor.author
Giambastiani, Giuliano
dc.contributor.author
Masi, Dante
dc.contributor.author
Parisel, Sebastien L.
dc.contributor.author
Togni, Antonio
dc.date.accessioned
2024-07-24T13:25:53Z
dc.date.available
2024-07-24T13:18:35Z
dc.date.available
2024-07-24T13:25:53Z
dc.date.issued
2004-02
dc.identifier.issn
0039-7881
dc.identifier.issn
1437-210X
dc.identifier.other
10.1055/s-2003-44378
en_US
dc.identifier.uri
http://hdl.handle.net/20.500.11850/685046
dc.description.abstract
Two new diastereomeric ferrocenyl triphosphine ligands P3Chir 1 and 2 have been conveniently synthesized through a multi-step reaction sequence starting from (R)-(S)-diphenylphosphinoferrocenylamine [(R)-(S)-PPFA]. Chromatographic resolution of the diborane protected-phosphine oxide derivatives, followed by a stereoconservative reduction/deboronation step, gave the pure triphosphines P3Chir in which the planar chirality of the ferrocenyl unit is combined with phosphorus and carbon stereocenters in an unprecedented molecular assembly.
en_US
dc.language.iso
en
en_US
dc.publisher
Thieme
en_US
dc.subject
Chiral
en_US
dc.subject
Ferrocenes
en_US
dc.subject
Phosphines
en_US
dc.subject
Tridentate ligands
en_US
dc.subject
Chromatographic resolution
en_US
dc.title
Synthetic Approaches to New Diastereomerically Pure Ferrocenyl Trisphosphines Combining Phosphorus, Planar, and Carbon Chirality
en_US
dc.type
Journal Article
dc.date.published
2003-12-15
ethz.journal.title
Synthesis
ethz.journal.volume
2004
en_US
ethz.journal.issue
3
en_US
ethz.pages.start
345
en_US
ethz.pages.end
352
en_US
ethz.identifier.wos
ethz.publication.place
Stuttgart
ethz.publication.status
published
en_US
ethz.leitzahl
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03363 - Togni, Antonio (emeritus) / Togni, Antonio (emeritus)
en_US
ethz.leitzahl.certified
ETH Zürich::00002 - ETH Zürich::00012 - Lehre und Forschung::00007 - Departemente::02020 - Dep. Chemie und Angewandte Biowiss. / Dep. of Chemistry and Applied Biosc.::02513 - Laboratorium für Anorganische Chemie / Laboratory of Inorganic Chemistry::03363 - Togni, Antonio (emeritus) / Togni, Antonio (emeritus)
ethz.date.deposited
2017-06-10T02:31:21Z
ethz.source
ECIT
ethz.identifier.importid
imp593652efb102619784
ethz.identifier.importid
imp59364f71320d246470
ethz.ecitpid
pub:153523
ethz.ecitpid
pub:84388
ethz.eth
yes
en_US
ethz.availability
Metadata only
en_US
ethz.rosetta.installDate
2024-07-24T13:18:36Z
ethz.rosetta.lastUpdated
2024-07-24T13:18:36Z
ethz.rosetta.exportRequired
true
ethz.rosetta.versionExported
true
dc.identifier.olduri
http://hdl.handle.net/20.500.11850/164275
dc.identifier.olduri
http://hdl.handle.net/20.500.11850/51804
ethz.COinS
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