Raffael Aellig


Last Name

Aellig

First Name

Raffael

ORCID

0000-0002-9032-8645

Organisational unit

Filters

2019 - 201912020 - 20231
Reset filters

Search Results

Publications 1 - 2 of 2
  • Exploring hail and lightning diagnostics over the Alpine-Adriatic region in a km-scale climate model
    Item type: Journal Article
    Cui, Ruoyi; Ban, Nikolina; Demory, Marie-Estelle; et al. (2023)
    Weather and Climate Dynamics
    The north and south of the Alps, as well as the eastern shores of the Adriatic Sea, are hot spots of severe convective storms, including hail and lightning associated with deep convection. With advancements in computing power, it has become feasible to simulate deep convection explicitly in climate models by decreasing the horizontal grid spacing to less than 4 km. These kilometer-scale models improve the representation of orography and reduce uncertainties associated with the use of deep convection parameterizations. In this study, we perform km-scale simulations for eight observed cases of severe convective storms (seven with and one without observed hail) over the Alpine-Adriatic region. The simulations are performed with the climate version of the regional model Consortium for Small-scale Modeling (COSMO) that runs on graphics processing units (GPUs) at a horizontal grid spacing of 2.2 km. To analyze hail and lightning we have explored the hail growth model (HAILCAST) and lightning potential index (LPI) diagnostics integrated with the COSMO-crCLIM model. Comparison with available high-resolution observations reveals good performance of the model in simulating total precipitation, hail, and lightning. By performing a detailed analysis of three of the case studies, we identified the importance of significant meteorological factors for heavy thunderstorms that were reproduced by the model. Among these are the moist unstable boundary layer and dry mid-level air, the topographic barrier, as well as an approaching upper-level trough and cold front. Although COSMO HAILCAST tends to underestimate the hail size on the ground, the results indicate that both HAILCAST and LPI are promising candidates for future climate research.
  • Halogen activation and radical cycling initiated by imidazole-2-carboxaldehyde photochemistry
    Item type: Journal Article
    Corral Arroyo, Pablo; Aellig, Raffael; Alpert, Peter A.; et al. (2019)
    Atmospheric Chemistry and Physics
    Atmospheric aerosol particles can contain light-absorbing organic compounds, also referred to as brown carbon (BrC). The ocean surface and sea spray aerosol particles can also contain light-absorbing organic species referred to as chromophoric dissolved organic matter (CDOM). Many BrC and CDOM species can contain carbonyls, dicarbonyls or aromatic carbonyls such as imidazole-2-carboxaldehyde (IC), which may act as photosensitizers because they form triplet excited states upon UV–VIS light absorption. These triplet excited states are strong oxidants and may initiate catalytic radical reaction cycles within and at the surface of atmospheric aerosol particles, thereby increasing the production of condensed-phase reactive oxygen species (ROS). Triplet states or ROS can also react with halides, generating halogen radicals and molecular halogen compounds. In particular, molecular halogens can be released into the gas phase, which is one halogen activation pathway. In this work, we studied the influence of bromide and iodide on the photosensitized production and release of hydroperoxy radicals (HO2) upon UV irradiation of films in a coated wall flow tube (CWFT) containing IC in a matrix of citric acid (CA) irradiated with UV light. In addition, we measured the iodine release upon irradiation of IC ∕ CA films in the CWFT. We developed a kinetic model coupling photosensitized CA oxidation with condensed-phase halogen chemistry to support data analysis and assessment of atmospheric implications in terms of HO2 production and halogen release in sea spray particles. As indicated by the experimental results and confirmed by the model, significant recycling of halogen species occurred via scavenging reactions with HO2. These prevented the full and immediate release of the molecular halogen (bromine and iodine) produced. Recycling was stronger at low relative humidity, attributed to diffusion limitations. Our findings also show that the HO2 production from BrC or CDOM photosensitized reactions can increase due to the presence of halides, leading to high HO2 turnover, in spite of low release due to the scavenging reactions. We estimated the iodine production within sea salt aerosol particles due to iodide oxidation by ozone (O3) at 5.0×10−6 M s−1 assuming O3 was in Henry's law equilibrium with the particle. However, using an O3 diffusion coefficient of 1×10−12 cm2 s−1, iodine activation in an aged, organic-rich sea spray is estimated to be 5.5×10−8 M s−1. The estimated iodine production from BrC photochemistry based on the results reported here amounts to 4.1×10−7 M s−1 and indicates that BrC photochemistry can exceed O3 reactive uptake in controlling the rates of iodine activation from sea spray particles under dry or cold conditions where diffusion is slow within particles.
Publications 1 - 2 of 2