New magnetic frameworks of (CuF2(H2O)(2))(x)(pyz)
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Date
2014
Publication Type
Journal Article
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yes
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Abstract
Pressure-driven orbital reordering in the quantum magnet [CuF2(H2O)2(pyz)], (pyz = pyrazine), dramatically affects its magnetic exchange interactions. The crystal chemistry of this system is enriched with a new phase above 3 GPa, surprisingly concomitant with other polymorphs. Moreover, we discovered an unprecedented compound with a different stoichiometry, [(CuF2(H2O)2)2(pyz)], featuring magnetic bi-layers.
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published
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Journal / series
Volume
50 (93)
Pages / Article No.
14504 - 14507
Publisher
Royal Society of Chemistry