Simple conversion of trisodium phosphide, Na3P, into silyl- and cyanophosphides and the structure of a terminal silver phosphide


Loading...

Date

2022-03-07

Publication Type

Journal Article

ETH Bibliography

yes

Citations

Altmetric

Data

Abstract

A reaction of trisodium phosphide (Na3P) with chlorosilanes allows for simple derivatization into silyl- and cyano-substituted phosphanide species which were compared with each other. The recently discovered cyano(triphenylsilyl)phosphanide shows unique coordination properties compared to bis(silyl)phosphides.

Publication status

published

Editor

Book title

Volume

51 (9)

Pages / Article No.

3497 - 3501

Publisher

Royal Society of Chemistry

Event

Edition / version

Methods

Software

Geographic location

Date collected

Date created

Subject

Organisational unit

03447 - Grützmacher, Hansjörg (emeritus) / Grützmacher, Hansjörg (emeritus) check_circle

Notes

Funding

Related publications and datasets