Like Early Starvation 1 and Early Starvation 1 Promote and Stabilize Amylopectin Phase Transition in Starch Biosynthesis


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Date

2023-05

Publication Type

Journal Article

ETH Bibliography

yes

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Abstract

Starch, the most abundant carbohydrate reserve in plants, primarily consists of the branched glucan amylopectin, which forms semi-crystalline granules. Phase transition from a soluble to an insoluble form depends on amylopectin architecture, requiring a compatible distribution of glucan chain lengths and a branch-point distribution. Here, we show that two starch-bound proteins, LIKE EARLY STARVATION 1 (LESV) and EARLY STARVATION 1 (ESV1), which have unusual carbohydrate-binding surfaces, promote the phase transition of amylopectin-like glucans, both in a heterologous yeast system expressing the starch biosynthetic machinery and in Arabidopsis plants. We propose a model wherein LESV serves as a nucleating role, with its carbohydrate-binding surfaces helping align glucan double helices to promote their phase transition into semi-crystalline lamellae, which are then stabilized by ESV1. Because both proteins are widely conserved, we suggest that protein-facilitated glucan crystallization may be a general and previously unrecognized feature of starch biosynthesis.

Publication status

published

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Volume

9 (21)

Pages / Article No.

Publisher

AAAS

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Organisational unit

03707 - Zeeman, Samuel C. / Zeeman, Samuel C. check_circle

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Funding

182570 - Understanding the Cell Biology of Starch Metabolism in Plants (SNF)

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