Evolution and Future Directions of Metal-Free Atom Transfer Radical Polymerization
OPEN ACCESS
Author / Producer
Date
2018-10-09
Publication Type
Journal Article
ETH Bibliography
no
Citations
Altmetric
OPEN ACCESS
Data
Rights / License
Abstract
The increasing impact of atom transfer radical polymerization (ATRP) in fields beyond traditional polymer science has necessitated the development of alternative strategies for controlling polymer growth. Driven by applications that are sensitive to metal ion contamination, “greener” methodologies are emerging as a powerful alternative to conventional ATRP. Organic catalysis represents a major evolution of ATRP with metal-free systems holding significant potential as user-friendly methods for utility in biological and microelectronic applications. In addition, shifting from a combination of thermal activation/metal ions/ligands to simpler organic catalysis/light activation increases compatibility with functional monomers and allows the development of novel surface patterning strategies. Herein, we highlight key discoveries and recent developments in metal-free ATRP, while providing a perspective for future opportunities in this emerging area.
Permanent link
Publication status
published
External links
Editor
Book title
Journal / series
Volume
51 (19)
Pages / Article No.
7421 - 7434
Publisher
American Chemical Society
Event
Edition / version
Methods
Software
Geographic location
Date collected
Date created
Subject
Organisational unit
09644 - Anastasaki, Athina / Anastasaki, Athina