Role of the pea protein aggregation state on their interfacial properties


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Date

2024-03-15

Publication Type

Journal Article

ETH Bibliography

yes

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Data

Abstract

Hypothesis: Plant protein ingredients from similar sources can vary in functionality not only because of compositional differences, but also because of differences in their structure depending on their processing history. It is essential to understand these distinctions to develop novel food emulsion using plant proteins. It is hypothesized that differing interfacial properties can be attributed to their structures, aggregation, and colloidal states. Experiments: The adsorption behavior of a commercial protein isolate, homogenized or non-homogenized, was compared to a mildly extracted isolate to evaluate the effect of aggregation state and structural differences. After characterization of the particle size and protein composition, the interfacial properties were compared. Findings: Atomic force microscopy provided evidence of interfaces packed with protein oligomers regardless of the treatment. Differences in adsorption kinetics and interfacial shear rheology depending on oil polarity suggested different interfacial structures. A polydisperse mixture of protein oligomers resulted in increased rearrangements and protein-protein interactions at the interface. Homogenization of commercial proteins resulted in a lower interfacial tension and less elastic interfaces compared to those of native proteins due to the presence of larger aggregates. This study highlights how the interfacial properties can be related to the protein aggregation state resulting from differences in processing history.

Publication status

published

Editor

Book title

Volume

658

Pages / Article No.

156 - 166

Publisher

Elsevier

Event

Edition / version

Methods

Software

Geographic location

Date collected

Date created

Subject

Plant proteins; Pea protein; Colloidal state; Interfacial behavior; Food emulsions; Oil-water interface

Organisational unit

08821 - Fischer, Peter (Tit.-Prof.) check_circle

Notes

Funding

212079 - Green proteins: Do we have to rethink food emulsion? (SNF)

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