Induction of Intracellular Reductive Stress with a Photoactivatable Phosphine Probe


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Date

2018-04

Publication Type

Journal Article

ETH Bibliography

yes

Citations

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Data

Abstract

Reductive stress is a condition present in cells that have an increased concentration of reducing species, and it has been associated with a number of pathologies, such as neurodegenerative diseases and cancer. The tools available to study reductive stress lack both in selectivity and specific targeting and some of these shortcomings can be addressed by using photoactivatable compounds. We developed a photoactivatable phosphonium probe, which upon irradiation releases a fluorescent molecule and a trialkyphosphine. The probes can permeate through the plasma membrane and the photoreleased phosphine can induce intracellular reductive stress as proven by the detection of protein aggregates.

Publication status

published

Editor

Book title

Journal / series

Volume

72 (4)

Pages / Article No.

241 - 244

Publisher

Swiss Chemical Society

Event

Edition / version

Methods

Geographic location

Date collected

Date created

Subject

Photoactivation; Protein aggregation; Reductive stress; Tributylphosphine

Organisational unit

09551 - Rivera Fuentes, Pablo M. (ehemalig) / Rivera Fuentes, Pablo M. (former) check_circle

Notes

Funding Info about funding

165551 - Development of Intracellular Photoactivatable Probes (SNF)

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