Synthesis of α,β-Unsaturated Amides by Olefin Cross-Metathesis

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Author / Producer

Chatterjee, Arnab K. Grubbs, Robert H.

Date

2001-04-01

Publication Type

Journal Article

ETH Bibliography

no

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Abstract

Electronic and steric properties of the substituents on the amide nitrogen atom govern the yield and rate of the cross-metathesis between a variety of α,β-unsaturated amides and olefins with 1 as the catalyst. This influence is the result of deactivation of the catalyst by chelation of the carbonyl group to the metal. However, an increase in catalyst loading compensates for the chelation effect.

Permanent link

http://hdl.handle.net/20.500.11850/537090

Publication status

published

External links

https://doi.org/10.1002/1521-3773(20010401)40:7<1277::aid-anie1277>3.0.co;2-e north_east

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Book title

Journal / series

Volume

40 (7)

Pages / Article No.

1277 - 1279

Publisher

Wiley-VCH

Event

Edition / version

Methods

Software

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Date collected

Date created

Subject

Organisational unit

09767 - Choi, Tae-Lim / Choi, Tae-Lim check_circle

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