Synthesis and Reactivity of a Pentacoordinated Thiolate-Based Imido-Alkylidene W(VI) Complexes
Open access
Date
2016Type
- Journal Article
ETH Bibliography
yes
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Abstract
Attempt to synthesize a bis-thiolate tungsten alkylidene catalysts with bulky arenethiolates unexpectedly yielded upon activation of DME a pentacoordinated complex of general formula [W(NAr)(CHCMe3)(SAr’)(κ2-O-CH2-CH2-OMe)], which is active towards self-metathesis of cis-4-nonene compared to the parent bis-benzenethiolate. Show more
Permanent link
https://doi.org/10.3929/ethz-b-000115847Publication status
publishedExternal links
Journal / series
Oil & Gas Science and Technology – Revue d’IFP Energies nouvellesVolume
Pages / Article No.
Publisher
Editions TechnipOrganisational unit
03872 - Copéret, Christophe / Copéret, Christophe
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ETH Bibliography
yes
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