Abstract
The reaction between [$Ru_2Cl_2(μ_2-Cl)_2(CO)_6]$ and the biradicaloid [$P(μ-NTer)]_2$ proceeds under insertion of a $Ru(II)Cl(CO)_2$ fragment into one $P-N$ bond and addition of chloride to the adjacent phosphorus center. Thereby an unprecedented inorganic ruthenacycle is obtained that was investigated by single crystal X-ray analysis, $NMR$ and $IR$ pectroscopy and $DFT$ calculations. The reactivity of the complex in a halide-pseudo-halide exchange reaction and a coordination reaction were investigated. Show more
Permanent link
https://doi.org/10.3929/ethz-b-000543772Publication status
publishedExternal links
Journal / series
Zeitschrift für anorganische und allgemeine ChemieVolume
Pages / Article No.
Publisher
Wiley-VCHSubject
Phosphorus heterocycles; Ruthenium; Metallacycles; Coordination chemistry; N,P ligandsOrganisational unit
03447 - Grützmacher, Hansjörg / Grützmacher, Hansjörg
02024 - Small Molecule Crystallography Center
Funding
181966 - Coordinated radicals and catalyzed dehydrogenation reactions II (SNF)
ETH-36 17-2 - Phosphaethynolate as building block for Heterocycles and Metal Phosphides (ETHZ)
More
Show all metadata
ETH Bibliography
yes
Altmetrics